PMID- 25520180 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20150407 LR - 20240322 IS - 2045-2322 (Electronic) IS - 2045-2322 (Linking) VI - 4 DP - 2014 Dec 18 TI - Fabrication of Ni-Ti-O nanotube arrays by anodization of NiTi alloy and their potential applications. PG - 7547 LID - 10.1038/srep07547 [doi] LID - 7547 AB - Nickel-titanium-oxide (Ni-Ti-O) nanotube arrays (NTAs) prepared on nearly equiatomic NiTi alloy shall have broad application potential such as for energy storage and biomedicine, but their precise structure control is a great challenge because of the high content of alloying element of Ni, a non-valve metal that cannot form a compact electronic insulating passive layer when anodized. In the present work, we systemically investigated the influence of various anodization parameters on the formation and structure of Ni-Ti-O NTAs and their potential applications. Our results show that well controlled NTAs can be fabricated during relatively wide ranges of the anodization voltage (5-90 V), electrolyte temperature (10-50 degrees C) and electrolyte NH4F content (0.025-0.8 wt%) but within a narrow window of the electrolyte H2O content (0.0-1.0 vol%). Through modulating these parameters, the Ni-Ti-O NTAs with different diameter (15-70 nm) and length (45-1320 nm) can be produced in a controlled manner. Regarding potential applications, the Ni-Ti-O NTAs may be used as electrodes for electrochemical energy storage and non-enzymic glucose detection, and may constitute nanoscaled biofunctional coating to improve the biological performance of NiTi based biomedical implants. FAU - Hang, Ruiqiang AU - Hang R AD - Research Institute of Surface Engineering, Taiyuan University of Technology No. 79 Yingze West Road, Taiyuan 030024, China. FAU - Liu, Yanlian AU - Liu Y AD - Research Institute of Surface Engineering, Taiyuan University of Technology No. 79 Yingze West Road, Taiyuan 030024, China. FAU - Zhao, Lingzhou AU - Zhao L AD - State Key Laboratory of Military Stomatology, Department of Periodontology, School of Stomatology, The Fourth Military Medical University No. 145 West Changle Road, Xi'an 710032, China. FAU - Gao, Ang AU - Gao A AD - Department of Physics and Materials Science, City University of Hong Kong Tat Chee Avenue, Kowloon, Hong Kong, China. FAU - Bai, Long AU - Bai L AD - Research Institute of Surface Engineering, Taiyuan University of Technology No. 79 Yingze West Road, Taiyuan 030024, China. FAU - Huang, Xiaobo AU - Huang X AD - Research Institute of Surface Engineering, Taiyuan University of Technology No. 79 Yingze West Road, Taiyuan 030024, China. FAU - Zhang, Xiangyu AU - Zhang X AD - Research Institute of Surface Engineering, Taiyuan University of Technology No. 79 Yingze West Road, Taiyuan 030024, China. FAU - Tang, Bin AU - Tang B AD - Research Institute of Surface Engineering, Taiyuan University of Technology No. 79 Yingze West Road, Taiyuan 030024, China. FAU - Chu, Paul K AU - Chu PK AD - Department of Physics and Materials Science, City University of Hong Kong Tat Chee Avenue, Kowloon, Hong Kong, China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20141218 PL - England TA - Sci Rep JT - Scientific reports JID - 101563288 PMC - PMC4269879 EDAT- 2014/12/19 06:00 MHDA- 2014/12/19 06:01 PMCR- 2014/12/18 CRDT- 2014/12/19 06:00 PHST- 2014/07/02 00:00 [received] PHST- 2014/12/01 00:00 [accepted] PHST- 2014/12/19 06:00 [entrez] PHST- 2014/12/19 06:00 [pubmed] PHST- 2014/12/19 06:01 [medline] PHST- 2014/12/18 00:00 [pmc-release] AID - srep07547 [pii] AID - 10.1038/srep07547 [doi] PST - epublish SO - Sci Rep. 2014 Dec 18;4:7547. doi: 10.1038/srep07547.