PMID- 25532672 OWN - NLM STAT- MEDLINE DCOM- 20151001 LR - 20150127 IS - 1879-2456 (Electronic) IS - 0956-053X (Linking) VI - 36 DP - 2015 Feb TI - Enhanced diesel fuel fraction from waste high-density polyethylene and heavy gas oil pyrolysis using factorial design methodology. PG - 166-76 LID - S0956-053X(14)00573-X [pii] LID - 10.1016/j.wasman.2014.11.023 [doi] AB - Factorial Design Methodology (FDM) was developed to enhance diesel fuel fraction (C9-C23) from waste high-density polyethylene (HDPE) and Heavy Gas Oil (HGO) through co-pyrolysis. FDM was used for optimization of the following reaction parameters: temperature, catalyst and HDPE amounts. The HGO amount was constant (2.00 g) in all experiments. The model optimum conditions were determined to be temperature of 550 degrees C, HDPE = 0.20 g and no FCC catalyst. Under such conditions, 94% of pyrolytic oil was recovered, of which diesel fuel fraction was 93% (87% diesel fuel fraction yield), no residue was produced and 6% of noncondensable gaseous/volatile fraction was obtained. Seeking to reduce the cost due to high process temperatures, the impact of using higher catalyst content (25%) with a lower temperature (500 degrees C) was investigated. Under these conditions, 88% of pyrolytic oil was recovered (diesel fuel fraction yield was also 87%) as well as 12% of the noncondensable gaseous/volatile fraction. No waste was produced in these conditions, being an environmentally friendly approach for recycling the waste plastic. This paper demonstrated the usefulness of using FDM to predict and to optimize diesel fuel fraction yield with a great reduction in the number of experiments. CI - Copyright (c) 2014 Elsevier Ltd. All rights reserved. FAU - Joppert, Ney Jr AU - Joppert N Jr AD - Laboratorio de Tecnologia Ambiental, Instituto de Quimica, Universidade do Estado do Rio de Janeiro, Rio de Janeiro, Brazil. FAU - da Silva, Alexsandro Araujo AU - da Silva AA AD - Laboratorio de Tecnologia Ambiental, Instituto de Quimica, Universidade do Estado do Rio de Janeiro, Rio de Janeiro, Brazil. FAU - da Costa Marques, Monica Regina AU - da Costa Marques MR AD - Laboratorio de Tecnologia Ambiental, Instituto de Quimica, Universidade do Estado do Rio de Janeiro, Rio de Janeiro, Brazil. Electronic address: monicamarques@uerj.br. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20141219 PL - United States TA - Waste Manag JT - Waste management (New York, N.Y.) JID - 9884362 RN - 0 (Gasoline) RN - 0 (Plastics) RN - 9002-88-4 (Polyethylene) SB - IM MH - Gasoline/*analysis MH - Incineration/*methods MH - Plastics/chemistry MH - Polyethylene/*chemistry MH - Product Packaging MH - Recycling/*methods MH - *Renewable Energy OTO - NOTNLM OT - Factorial design methodology OT - Heavy gas oil OT - High density polyethylene waste OT - Pyrolysis EDAT- 2014/12/24 06:00 MHDA- 2015/10/02 06:00 CRDT- 2014/12/24 06:00 PHST- 2014/09/03 00:00 [received] PHST- 2014/11/26 00:00 [revised] PHST- 2014/11/27 00:00 [accepted] PHST- 2014/12/24 06:00 [entrez] PHST- 2014/12/24 06:00 [pubmed] PHST- 2015/10/02 06:00 [medline] AID - S0956-053X(14)00573-X [pii] AID - 10.1016/j.wasman.2014.11.023 [doi] PST - ppublish SO - Waste Manag. 2015 Feb;36:166-76. doi: 10.1016/j.wasman.2014.11.023. Epub 2014 Dec 19.