PMID- 25556870
OWN - NLM
STAT- MEDLINE
DCOM- 20150911
LR  - 20181202
IS  - 1095-8630 (Electronic)
IS  - 0301-4797 (Linking)
VI  - 150
DP  - 2015 Mar 1
TI  - Rapid degradation of endosulfan by zero-valent zinc in water and soil.
PG  - 451-455
LID - S0301-4797(14)00607-0 [pii]
LID - 10.1016/j.jenvman.2014.12.028 [doi]
AB  - Endosulfan has been included in the list of persistent organic pollutants (POPs) 
      in 2011. The degradation of endosulfan by zero-valent zinc in water and soil was 
      first investigated. The results showed that >90% endosulfan could be degraded in 
      180 min. The degradation was accelerated under acidic conditions with the absence 
      of dissolved oxygen, while the nature of the soil only exhibited a negligible 
      effect. The half-life was decreased from 130.75 min to 41.75 min with the 
      increment of Zn(0) from 0.1 g to 1 g in soil. The use of Zn(0) was more effective 
      than Fe(0) for the degradation of endosulfan with a half-life of 110 min and 
      330 min. The cationic surfactant was more effective at enhancing the degradation 
      of endosulfan than anionic and nonionic surfactant. The degradation pathway was 
      speculated, and four chlorine of endosulfan were proposed to be reduced. The 
      method exhibited obvious advantages over traditional endosulfan treatments, and 
      the research results will lay a foundation for practical application of the 
      method.
CI  - Copyright (c) 2014 Elsevier Ltd. All rights reserved.
FAU - Cong, Lujing
AU  - Cong L
AD  - Department of Pesticide Science, College of Plant Protection, Nanjing 
      Agricultural University, State & Local Joint Engineering Research Center of Green 
      Pesticide Invention and Application, Nanjing 210095, PR China.
FAU - Guo, Jing
AU  - Guo J
AD  - College of Sciences, Nanjing Agricultural University, Nanjing 210095, PR China.
FAU - Liu, Jisong
AU  - Liu J
AD  - Department of Pesticide Science, College of Plant Protection, Nanjing 
      Agricultural University, State & Local Joint Engineering Research Center of Green 
      Pesticide Invention and Application, Nanjing 210095, PR China.
FAU - Shi, Haiyan
AU  - Shi H
AD  - Department of Pesticide Science, College of Plant Protection, Nanjing 
      Agricultural University, State & Local Joint Engineering Research Center of Green 
      Pesticide Invention and Application, Nanjing 210095, PR China.
FAU - Wang, Minghua
AU  - Wang M
AD  - Department of Pesticide Science, College of Plant Protection, Nanjing 
      Agricultural University, State & Local Joint Engineering Research Center of Green 
      Pesticide Invention and Application, Nanjing 210095, PR China. Electronic 
      address: wangmha@njau.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20141231
PL  - England
TA  - J Environ Manage
JT  - Journal of environmental management
JID - 0401664
RN  - 0 (Insecticides)
RN  - 0 (Soil)
RN  - 0 (Soil Pollutants)
RN  - 0 (Water Pollutants)
RN  - 059QF0KO0R (Water)
RN  - J41CSQ7QDS (Zinc)
RN  - OKA6A6ZD4K (Endosulfan)
SB  - IM
MH  - Endosulfan/*chemistry
MH  - Environmental Restoration and Remediation
MH  - Humans
MH  - Insecticides/*chemistry
MH  - Soil/chemistry
MH  - Soil Pollutants/*chemistry
MH  - Water/chemistry
MH  - Water Pollutants/*chemistry
MH  - Zinc/*chemistry
OTO - NOTNLM
OT  - Endosulfan
OT  - POPs
OT  - Rapid degradation
OT  - Soil
OT  - Water
OT  - Zero-valent zinc
EDAT- 2015/01/06 06:00
MHDA- 2015/09/12 06:00
CRDT- 2015/01/06 06:00
PHST- 2014/10/10 00:00 [received]
PHST- 2014/12/09 00:00 [revised]
PHST- 2014/12/12 00:00 [accepted]
PHST- 2015/01/06 06:00 [entrez]
PHST- 2015/01/06 06:00 [pubmed]
PHST- 2015/09/12 06:00 [medline]
AID - S0301-4797(14)00607-0 [pii]
AID - 10.1016/j.jenvman.2014.12.028 [doi]
PST - ppublish
SO  - J Environ Manage. 2015 Mar 1;150:451-455. doi: 10.1016/j.jenvman.2014.12.028. 
      Epub 2014 Dec 31.