PMID- 25592874 OWN - NLM STAT- MEDLINE DCOM- 20151009 LR - 20181202 IS - 2050-7895 (Electronic) IS - 2050-7887 (Linking) VI - 17 IP - 3 DP - 2015 Mar TI - Spatial distribution of selected persistent organic pollutants (POPs) in Australia's atmosphere. PG - 525-32 LID - 10.1039/c4em00594e [doi] AB - A nation-wide passive air sampling campaign recorded concentrations of persistent organic pollutants in Australia's atmosphere in 2012. XAD-based passive air samplers were deployed for one year at 15 sampling sites located in remote/background, agricultural and semi-urban and urban areas across the continent. Concentrations of 47 polychlorinated biphenyls ranged from 0.73 to 72 pg m(-3) (median of 8.9 pg m(-3)) and were consistently higher at urban sites. The toxic equivalent concentration for the sum of 12 dioxin-like PCBs was low, ranging from below detection limits to 0.24 fg m(-3) (median of 0.0086 fg m(-3)). Overall, the levels of polychlorinated biphenyls in Australia were among the lowest reported globally to date. Among the organochlorine pesticides, hexachlorobenzene had the highest (median of 41 pg m(-3)) and most uniform concentration (with a ratio between highest and lowest value approximately 5). Bushfires may be responsible for atmospheric hexachlorobenzene levels in Australia that exceeded Southern Hemispheric baseline levels by a factor of approximately 4. Organochlorine pesticide concentrations generally increased from remote/background and agricultural sites to urban sites, except for high concentrations of alpha-endosulfan and DDTs at specific agricultural sites. Concentrations of heptachlor (0.47-210 pg m(-3)), dieldrin (ND-160 pg m(-3)) and trans- and cis-chlordanes (0.83-180 pg m(-3), sum of) in Australian air were among the highest reported globally to date, whereas those of DDT and its metabolites (ND-160 pg m(-3), sum of), alpha-, beta-, gamma- and delta-hexachlorocyclohexane (ND-6.7 pg m(-3), sum of) and alpha-endosulfan (ND-27 pg m(-3)) were among the lowest. FAU - Wang, Xianyu AU - Wang X AD - National Research Centre for Environmental Toxicology, The University of Queensland, 39 Kessels Road, Coopers Plains, QLD 4108, Australia. x.wang18@uq.edu.au. FAU - Kennedy, Karen AU - Kennedy K FAU - Powell, Jennifer AU - Powell J FAU - Keywood, Melita AU - Keywood M FAU - Gillett, Rob AU - Gillett R FAU - Thai, Phong AU - Thai P FAU - Bridgen, Phil AU - Bridgen P FAU - Broomhall, Sara AU - Broomhall S FAU - Paxman, Chris AU - Paxman C FAU - Wania, Frank AU - Wania F FAU - Mueller, Jochen F AU - Mueller JF LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - England TA - Environ Sci Process Impacts JT - Environmental science. Processes & impacts JID - 101601576 RN - 0 (Air Pollutants) RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticides) RN - 319-86-8 (delta-hexachlorocyclohexane) RN - 59NEE7PCAB (Hexachlorocyclohexane) RN - DFC2HB4I0K (Polychlorinated Biphenyls) RN - OKA6A6ZD4K (Endosulfan) SB - IM MH - Air Pollutants/*analysis MH - Air Pollution/statistics & numerical data MH - Atmosphere/*chemistry MH - Australia MH - Endosulfan MH - *Environmental Monitoring MH - Hexachlorocyclohexane MH - Hydrocarbons, Chlorinated/analysis MH - Pesticides/analysis MH - Polychlorinated Biphenyls/analysis EDAT- 2015/01/17 06:00 MHDA- 2015/10/10 06:00 CRDT- 2015/01/17 06:00 PHST- 2015/01/17 06:00 [entrez] PHST- 2015/01/17 06:00 [pubmed] PHST- 2015/10/10 06:00 [medline] AID - 10.1039/c4em00594e [doi] PST - ppublish SO - Environ Sci Process Impacts. 2015 Mar;17(3):525-32. doi: 10.1039/c4em00594e.