PMID- 25612139 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20150519 LR - 20150204 IS - 1477-9234 (Electronic) IS - 1477-9226 (Linking) VI - 44 IP - 7 DP - 2015 Feb 21 TI - Mesoporous Mn-Zr composite oxides with a crystalline wall: synthesis, characterization and application. PG - 2997-3001 LID - 10.1039/c4dt03835e [doi] AB - Mesoporous Mn-Zr composite oxides (M-MnZr) with a crystalline wall were designed and achieved by a facile one-pot evaporation-induced self-assembly (EISA) strategy. As proved by XRD, HRTEM and SAED characterization, the wall of the obtained mesoporous materials exhibited a typical tetragonal phase of ZrO2. In addition, the introduced manganese species were homogeneously dispersed in the mesoporous skeleton. N2-physisorption and TEM results showed that all the final materials possessed an obvious mesoporous structure accompanied by a large specific surface area ( approximately 120 m(2) g(-1)), big pore volume ( approximately 0.2 cm(3) g(-1)) and uniform pore size ( approximately 4.9 nm). In addition, the liquid phase oxidation was chosen as the test reaction and the excellent catalytic performance of M-MnZr demonstrated their potential applications in oxidation reactions. FAU - Miao, Zhichao AU - Miao Z AD - State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, People's Republic of China. ljchou@licp.cas.cn. FAU - Zhao, Huahua AU - Zhao H FAU - Yang, Jian AU - Yang J FAU - Zhao, Jun AU - Zhao J FAU - Song, Huanling AU - Song H FAU - Chou, Lingjun AU - Chou L LA - eng PT - Journal Article PL - England TA - Dalton Trans JT - Dalton transactions (Cambridge, England : 2003) JID - 101176026 EDAT- 2015/01/23 06:00 MHDA- 2015/01/23 06:01 CRDT- 2015/01/23 06:00 PHST- 2015/01/23 06:00 [entrez] PHST- 2015/01/23 06:00 [pubmed] PHST- 2015/01/23 06:01 [medline] AID - 10.1039/c4dt03835e [doi] PST - ppublish SO - Dalton Trans. 2015 Feb 21;44(7):2997-3001. doi: 10.1039/c4dt03835e.