PMID- 25648222
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20150611
LR  - 20150317
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 54
IP  - 13
DP  - 2015 Mar 23
TI  - Ligand-promoted oxidative cross-coupling of aryl boronic acids and aryl silanes 
      by palladium catalysis.
PG  - 4079-82
LID - 10.1002/anie.201412288 [doi]
AB  - The first cross-coupling reaction between aryl silanes and aryl boronic acids is 
      described. This transformation represents one of the very few examples of 
      coupling reactions between two nucleophilic organometallic reagents and provides 
      a new method for the formation of biaryl compounds. The successful development of 
      this reaction was enabled by the use of commercially available 
      2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) as the ligand. A small amount 
      of BINAP (3 mol %) was sufficient to suppress the formation of the homocoupling 
      products, and the reaction yielded the cross-coupling products with high 
      selectivity under mild conditions, even when the ratio of the two coupling 
      partners was 1:1.
CI  - (c) 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Yu, Jingxun
AU  - Yu J
AD  - Department of Chemistry, Shanghai Key Laboratory of Chemical Assessment and 
      Sustainability, Tongji University, Shanghai 200092, Shanghai (P. R. China).
FAU - Liu, Jun
AU  - Liu J
FAU - Shi, Guangfa
AU  - Shi G
FAU - Shao, Changdong
AU  - Shao C
FAU - Zhang, Yanghui
AU  - Zhang Y
LA  - eng
PT  - Journal Article
DEP - 20150203
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
OTO - NOTNLM
OT  - cross-coupling
OT  - ligands
OT  - organoboron compounds
OT  - organosilicon compounds
OT  - palladium catalysis
EDAT- 2015/02/05 06:00
MHDA- 2015/02/05 06:01
CRDT- 2015/02/05 06:00
PHST- 2014/12/22 00:00 [received]
PHST- 2015/02/05 06:00 [entrez]
PHST- 2015/02/05 06:00 [pubmed]
PHST- 2015/02/05 06:01 [medline]
AID - 10.1002/anie.201412288 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2015 Mar 23;54(13):4079-82. doi: 10.1002/anie.201412288. 
      Epub 2015 Feb 3.