PMID- 25680551
OWN - NLM
STAT- MEDLINE
DCOM- 20150625
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1385
DP  - 2015 Mar 13
TI  - Monitoring of selected estrogen mimics in complicated samples using polymeric 
      ionic liquid-based multiple monolithic fiber solid-phase microextraction combined 
      with high-performance liquid chromatography.
PG  - 12-9
LID - S0021-9673(15)00168-5 [pii]
LID - 10.1016/j.chroma.2015.01.072 [doi]
AB  - A convenient, rapid, sensitive and environmentally friendly method for 
      simultaneous monitoring of six estrogen mimics (bisphenol A, diethylstilbestrol, 
      dienestrol, hexestrol, octylphenol and nonylphenol) in water and milk samples was 
      developed by coupling multiple monolithic fiber solid-phase microextraction 
      (MMF-SPME) to high performance liquid chromatography with diode array detection. 
      The MMF-SPME based on polymeric ionic liquid-based monolith as extractive medium 
      was used to concentrate target analytes. Because there were multiple interactions 
      between adsorbent and analytes, the MMF-SPME exhibited a high extractive 
      capability toward analytes. To obtain optimum extraction performance, several 
      extraction parameters including desorption solvent, pH value and ionic strength 
      in sample matrix, extraction and desorption time were investigated and discussed. 
      Under the optimized extraction conditions, the limits of detection (S/N=3) of the 
      proposed method were 0.040-0.11 mug/L in water and in milk samples. Satisfactory 
      linearity was achieved for analytes with the correlation coefficients (r) above 
      0.99. Excellent method reproducibility was achieved by evaluating the 
      repeatability, intermediate precision and MMF-to-MMF reproducibility with 
      relative standard deviations (RSDs) of both less than 10%. Finally, the proposed 
      method was successfully applied to the determination of estrogen mimics in 
      several milk and environmental water samples. Recoveries obtained for the 
      determination of six target analytes in spiking samples ranged from 75.6% to 
      118%, with RSD below 10% in all cases.
CI  - Copyright (c) 2015 Elsevier B.V. All rights reserved.
FAU - Mei, Meng
AU  - Mei M
AD  - State Key Laboratory of Marine Environmental Science, Key Laboratory of the 
      Ministry of Education for Coastal and Wetland Ecosystem, College of the 
      Environment and Ecology, Xiamen University, Xiamen 361005, China.
FAU - Yu, Jie
AU  - Yu J
AD  - State Key Laboratory of Marine Environmental Science, Key Laboratory of the 
      Ministry of Education for Coastal and Wetland Ecosystem, College of the 
      Environment and Ecology, Xiamen University, Xiamen 361005, China.
FAU - Huang, Xiaojia
AU  - Huang X
AD  - State Key Laboratory of Marine Environmental Science, Key Laboratory of the 
      Ministry of Education for Coastal and Wetland Ecosystem, College of the 
      Environment and Ecology, Xiamen University, Xiamen 361005, China. Electronic 
      address: hxj@xmu.edu.cn.
FAU - Li, Haonan
AU  - Li H
AD  - State Key Laboratory of Marine Environmental Science, Key Laboratory of the 
      Ministry of Education for Coastal and Wetland Ecosystem, College of the 
      Environment and Ecology, Xiamen University, Xiamen 361005, China.
FAU - Lin, Lan
AU  - Lin L
AD  - State Key Laboratory of Marine Environmental Science, Key Laboratory of the 
      Ministry of Education for Coastal and Wetland Ecosystem, College of the 
      Environment and Ecology, Xiamen University, Xiamen 361005, China.
FAU - Yuan, Dongxing
AU  - Yuan D
AD  - State Key Laboratory of Marine Environmental Science, Key Laboratory of the 
      Ministry of Education for Coastal and Wetland Ecosystem, College of the 
      Environment and Ecology, Xiamen University, Xiamen 361005, China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20150202
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Benzhydryl Compounds)
RN  - 0 (Estrogens)
RN  - 0 (Ionic Liquids)
RN  - 0 (Phenols)
RN  - 0 (octylphenol)
RN  - 059QF0KO0R (Water)
RN  - 79F6A2ILP5 (nonylphenol)
RN  - MLT3645I99 (bisphenol A)
SB  - IM
MH  - Animals
MH  - Benzhydryl Compounds/analysis
MH  - *Chromatography, High Pressure Liquid
MH  - Environmental Monitoring/*methods
MH  - Estrogens/*analysis
MH  - Ionic Liquids/chemistry
MH  - Limit of Detection
MH  - Milk/chemistry
MH  - Phenols/analysis
MH  - Reproducibility of Results
MH  - *Solid Phase Microextraction
MH  - Water/chemistry
OTO - NOTNLM
OT  - Environmental water
OT  - Estrogen mimics
OT  - Milk
OT  - Monolithic fiber solid-phase microextraction (MMF-SPME)
OT  - Polymeric ionic liquid
EDAT- 2015/02/15 06:00
MHDA- 2015/06/26 06:00
CRDT- 2015/02/15 06:00
PHST- 2014/12/04 00:00 [received]
PHST- 2015/01/22 00:00 [revised]
PHST- 2015/01/23 00:00 [accepted]
PHST- 2015/02/15 06:00 [entrez]
PHST- 2015/02/15 06:00 [pubmed]
PHST- 2015/06/26 06:00 [medline]
AID - S0021-9673(15)00168-5 [pii]
AID - 10.1016/j.chroma.2015.01.072 [doi]
PST - ppublish
SO  - J Chromatogr A. 2015 Mar 13;1385:12-9. doi: 10.1016/j.chroma.2015.01.072. Epub 
      2015 Feb 2.