PMID- 25683431
OWN - NLM
STAT- MEDLINE
DCOM- 20150817
LR  - 20191210
IS  - 1873-7072 (Electronic)
IS  - 0308-8146 (Linking)
VI  - 133
IP  - 2
DP  - 2012 Jul 15
TI  - Dispersive liquid-liquid microextraction combined with sweeping micellar 
      electrokinetic chromatography for the determination of some neonicotinoid 
      insecticides in cucumber samples.
PG  - 544-50
LID - S0308-8146(12)00061-1 [pii]
LID - 10.1016/j.foodchem.2012.01.028 [doi]
AB  - A rapid, simple and sensitive method has been developed for the analysis of some 
      neonicotinoid insecticides in cucumber samples by using dispersive liquid-liquid 
      microextraction (DLLME) coupled with sweeping in micellar electrokinetic 
      chromatography (MEKC). Under optimised conditions, the enrichment factors were 
      achieved in the range from 4000 to 10,000. The linearity of the method was in the 
      range from 2.7 to 200 ng g(-1) for thiacloprid, acetamiprid and imidacloprid, and 
      in the range from 4.0 to 200 ng g(-1) for imidaclothiz in cucumber samples, with 
      the determination coefficients (r(2)) ranging from 0.9924 to 0.9968. The limits 
      of detection (LODs, S/N=3) ranged from 0.8 to 1.2 ng g(-1). The relative standard 
      deviations (RSDs) at the concentration levels of 10.0 and 50.0 ng g(-1) each of 
      the neonicotinoid insecticides in cucumber samples varied from 3.8% to 6.3%. The 
      developed method has been successfully applied to the analysis of the 
      neonicotinoid insecticides in cucumbers with a satisfactory result.
CI  - Copyright (c) 2012 Elsevier Ltd. All rights reserved.
FAU - Zhang, Shuaihua
AU  - Zhang S
AD  - Key Laboratory of Bioinorganic Chemistry, College of Science, Agricultural 
      University of Hebei, Baoding 071001, Hebei, China.
FAU - Yang, Xiumin
AU  - Yang X
AD  - Key Laboratory of Bioinorganic Chemistry, College of Science, Agricultural 
      University of Hebei, Baoding 071001, Hebei, China.
FAU - Yin, Xiaofang
AU  - Yin X
AD  - Key Laboratory of Bioinorganic Chemistry, College of Science, Agricultural 
      University of Hebei, Baoding 071001, Hebei, China.
FAU - Wang, Chun
AU  - Wang C
AD  - Key Laboratory of Bioinorganic Chemistry, College of Science, Agricultural 
      University of Hebei, Baoding 071001, Hebei, China.
FAU - Wang, Zhi
AU  - Wang Z
AD  - Key Laboratory of Bioinorganic Chemistry, College of Science, Agricultural 
      University of Hebei, Baoding 071001, Hebei, China. Electronic address: 
      wangzhi@hebau.edu.cn.
LA  - eng
PT  - Evaluation Study
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20120125
PL  - England
TA  - Food Chem
JT  - Food chemistry
JID - 7702639
RN  - 0 (Imidazoles)
RN  - 0 (Insecticides)
RN  - 0 (Neonicotinoids)
RN  - 0 (Nitro Compounds)
RN  - 0 (Pyridines)
RN  - 0 (Thiazines)
RN  - 3BN7M937V8 (imidacloprid)
RN  - 5HL5N372P0 (acetamiprid)
RN  - DSV3A944A4 (thiacloprid)
SB  - IM
MH  - Chromatography, Micellar Electrokinetic Capillary/*methods
MH  - Cucumis sativus/*chemistry
MH  - Food Contamination
MH  - Imidazoles/analysis/isolation & purification
MH  - Insecticides/*analysis/*isolation & purification
MH  - Limit of Detection
MH  - Liquid Phase Microextraction/*methods
MH  - Neonicotinoids
MH  - Nitro Compounds/analysis/isolation & purification
MH  - Pyridines/analysis/isolation & purification
MH  - Thiazines/analysis/isolation & purification
OTO - NOTNLM
OT  - Cucumber samples
OT  - Dispersive liquid-liquid microextraction
OT  - Micellar electrokinetic chromatography
OT  - Neonicotinoid insecticides
OT  - Sweeping
EDAT- 2012/07/15 00:00
MHDA- 2015/08/19 06:00
CRDT- 2015/02/17 06:00
PHST- 2011/06/20 00:00 [received]
PHST- 2012/01/10 00:00 [revised]
PHST- 2012/01/14 00:00 [accepted]
PHST- 2015/02/17 06:00 [entrez]
PHST- 2012/07/15 00:00 [pubmed]
PHST- 2015/08/19 06:00 [medline]
AID - S0308-8146(12)00061-1 [pii]
AID - 10.1016/j.foodchem.2012.01.028 [doi]
PST - ppublish
SO  - Food Chem. 2012 Jul 15;133(2):544-50. doi: 10.1016/j.foodchem.2012.01.028. Epub 
      2012 Jan 25.