PMID- 25813026
OWN - NLM
STAT- MEDLINE
DCOM- 20151208
LR  - 20150327
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 867
DP  - 2015 Mar 31
TI  - In situ growth and phenyl functionalization of titania nanoparticles coating for 
      solid-phase microextraction of ultraviolet filters in environmental water samples 
      followed by high performance liquid chromatography-UV detection.
PG  - 38-46
LID - S0003-2670(15)00095-1 [pii]
LID - 10.1016/j.aca.2015.01.038 [doi]
AB  - Based on TiO2-nanoparticles coating fabricated by a one-step anodization method 
      on titanium wire substrate, a novel phenyl functionalized solid-phase 
      microextraction (SPME) fiber coating was prepared by simple and rapid in situ 
      chemical assembling technique between the fiber surface titanol groups and 
      trichlorophenylsilane reaction. The as-fabricated fiber exhibited good extraction 
      capability for some UV filters and was employed to determine the ultraviolet (UV) 
      filters in combination with high performance liquid chromatography-UV detection 
      (HPLC-UV). The main parameters affecting extraction performance were investigated 
      and optimized. Under the optimized conditions, the developed method was applied 
      to detect several UV filters at trace concentration levels with only 8 mL of 
      sample volume. They were determined in the range from 0.005 to 25 mug L(-1) with 
      detection limits (S/N=3) from 0.1 to 50 ng L(-1). The relative standard 
      deviations (RSDs) for single fiber repeatability varied from 4.6 to 6.5% (n=5) 
      and fiber-to-fiber reproducibility (n=5) ranged from 5.5 to 9.1%. The linear 
      ranges spanned two-four magnitudes with correlation coefficients above 0.9990. 
      Five real water samples including four Yellow River water samples and one rain 
      water sample were determined sensitively with good recoveries ranging from 86.2 
      to 105.5%. The functionalized fiber coating performed good reproducible manner, 
      high mechanical strength, good stability and long service life. Moreover, this 
      study proposed an efficient sample pretreatment method for the determination of 
      UV filters from environmental water samples.
CI  - Copyright (c) 2015 Elsevier B.V. All rights reserved.
FAU - Li, Li
AU  - Li L
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, PR China; College of Science, Gansu Agriculture University, 
      Lanzhou 730070, PR China.
FAU - Guo, Ruibin
AU  - Guo R
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, PR China.
FAU - Li, Yi
AU  - Li Y
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, PR China.
FAU - Guo, Mei
AU  - Guo M
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, PR China.
FAU - Wang, Xuemei
AU  - Wang X
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, PR China; Key Lab of Bioelectrochemistry & Environmental Analysis 
      of Gansu, Lanzhou 730070, PR China.
FAU - Du, Xinzhen
AU  - Du X
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou 730070, PR China; Key Lab of Bioelectrochemistry & Environmental Analysis 
      of Gansu, Lanzhou 730070, PR China. Electronic address: xinzhendu@yahoo.com.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20150130
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
RN  - 0 (Radiation-Protective Agents)
RN  - 0 (Silanes)
RN  - 0 (Water Pollutants, Chemical)
RN  - 15FIX9V2JP (titanium dioxide)
RN  - D1JT611TNE (Titanium)
SB  - IM
MH  - Chromatography, High Pressure Liquid/*methods
MH  - Fresh Water/*chemistry
MH  - Hydrogen-Ion Concentration
MH  - Hydrophobic and Hydrophilic Interactions
MH  - Nanoparticles/*chemistry
MH  - Nanotechnology
MH  - Osmolar Concentration
MH  - Radiation-Protective Agents/*analysis/chemistry/*isolation & purification
MH  - Silanes/chemistry
MH  - Solid Phase Microextraction/*methods
MH  - Spectrophotometry, Ultraviolet
MH  - Temperature
MH  - Time Factors
MH  - Titanium/*chemistry
MH  - Water Pollutants, Chemical/analysis/chemistry/isolation & purification
OTO - NOTNLM
OT  - Anodization
OT  - Solid-phase microextraction
OT  - TiO(2) nanoparticles
OT  - Trichlorophenylsilane
OT  - Ultraviolet filters
EDAT- 2015/03/31 06:00
MHDA- 2015/12/15 06:00
CRDT- 2015/03/28 06:00
PHST- 2014/11/15 00:00 [received]
PHST- 2015/01/21 00:00 [revised]
PHST- 2015/01/28 00:00 [accepted]
PHST- 2015/03/28 06:00 [entrez]
PHST- 2015/03/31 06:00 [pubmed]
PHST- 2015/12/15 06:00 [medline]
AID - S0003-2670(15)00095-1 [pii]
AID - 10.1016/j.aca.2015.01.038 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2015 Mar 31;867:38-46. doi: 10.1016/j.aca.2015.01.038. Epub 2015 
      Jan 30.