PMID- 25842313 OWN - NLM STAT- MEDLINE DCOM- 20160125 LR - 20181202 IS - 1873-7072 (Electronic) IS - 0308-8146 (Linking) VI - 182 DP - 2015 Sep 1 TI - Thermal and spectroscopic studies of the antioxidant food additive propyl gallate. PG - 89-94 LID - S0308-8146(15)00329-5 [pii] LID - 10.1016/j.foodchem.2015.02.129 [doi] AB - Literature mentions propyl gallate (PG) as a non-toxic synthetic antioxidant that can be used as a food additive due to its high tolerance to heat. It is important to understand the thermal properties and to identify the decomposition products of this substance, since it has been reported to be thermally stable at temperatures as high as 300 degrees C. Simultaneous thermogravimetry-differential thermal analysis (TG-DTA), differential scanning calorimetry-photovisual (DSC-photovisual), coupled thermogravimetry-infrared spectroscopy (TG-FTIR) analyses and spectroscopic techniques were used to study the food additive PG. The TG-DTA curves, which were performed with the aid of DSC-photovisual, provided information concerning the thermal stability and decomposition profiles of the compound. From the TG-FTIR coupled techniques, it was possible to identify n-propanol as a possible volatile compound released during the thermal decomposition of the antioxidant. A complete spectroscopic characterization in the ultraviolet, visible, near and middle infrared regions was performed in order to understand the spectroscopic properties of PG. CI - Copyright (c) 2015 Elsevier Ltd. All rights reserved. FAU - Galico, D A AU - Galico DA AD - UNESP - Univ Estadual Paulista, Faculdade de Ciencias, Departamento de Quimica, Sao Paulo CEP 17033-260, Brazil. FAU - Nova, C V AU - Nova CV AD - UNESP - Univ Estadual Paulista, Faculdade de Ciencias, Departamento de Quimica, Sao Paulo CEP 17033-260, Brazil. FAU - Guerra, R B AU - Guerra RB AD - UNESP - Univ Estadual Paulista, Faculdade de Ciencias, Departamento de Quimica, Sao Paulo CEP 17033-260, Brazil. FAU - Bannach, G AU - Bannach G AD - UNESP - Univ Estadual Paulista, Faculdade de Ciencias, Departamento de Quimica, Sao Paulo CEP 17033-260, Brazil. Electronic address: gilbert@fc.unesp.br. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20150304 PL - England TA - Food Chem JT - Food chemistry JID - 7702639 RN - 0 (Antioxidants) RN - 0 (Food Additives) RN - 8D4SNN7V92 (Propyl Gallate) SB - IM MH - Antioxidants MH - Calorimetry, Differential Scanning MH - Food Additives/*analysis MH - Propyl Gallate/*analysis MH - Spectrum Analysis/*methods OTO - NOTNLM OT - Coupled TG-FTIR OT - DSC-photovisual OT - Propyl gallate OT - Spectroscopic studies OT - Thermal behavior EDAT- 2015/04/07 06:00 MHDA- 2016/01/26 06:00 CRDT- 2015/04/06 06:00 PHST- 2014/12/16 00:00 [received] PHST- 2015/02/04 00:00 [revised] PHST- 2015/02/25 00:00 [accepted] PHST- 2015/04/06 06:00 [entrez] PHST- 2015/04/07 06:00 [pubmed] PHST- 2016/01/26 06:00 [medline] AID - S0308-8146(15)00329-5 [pii] AID - 10.1016/j.foodchem.2015.02.129 [doi] PST - ppublish SO - Food Chem. 2015 Sep 1;182:89-94. doi: 10.1016/j.foodchem.2015.02.129. Epub 2015 Mar 4.