PMID- 25994262 OWN - NLM STAT- MEDLINE DCOM- 20160511 LR - 20181202 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 22 IP - 19 DP - 2015 Oct TI - Effects of urbanization on gaseous and particulate polycyclic aromatic hydrocarbons and polychlorinated biphenyls in a coastal city, China: levels, sources, and health risks. PG - 14919-31 LID - 10.1007/s11356-015-4616-2 [doi] AB - Gas/particle distributions of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were measured in Xiamen from May 2009 to March 2010 to evaluate the impacts of urbanization on the fate of persistent organic pollutants (POPs) in the atmospheric environment. In a newly developing area (NDA), the concentrations of 16 PAHs (gas + particle) were significantly higher than that a historically urbanized area (HUA) (p value <0.05), while the trend of 28 PCBs was reversed. Diagnostic ratios and principle component analysis (PCA) implied that atmospheric PAHs in the NDA were mainly derived from petrogenic combustion, including mixed sources of vehicle emissions, biomass burning and oil combustion, while pyrogenic combustion (e.g., traffic and coal combustion) was considered the major source of PAHs in the HUA. Atmospheric PCBs in both HUA and NDA were dominated by TriCBs and PeCBs related to the use of commercial mixtures (Aroclors 1242 and 1254). Based on the toxicological equivalent factor (TEF) approach, total benzo[a]pyrene equivalent values in the HUA and NDA were 1.12 and 2.02 ng m(-3), respectively, exceeding the standard threshold values (1.0 ng m(-3)) of China and WHO. Average daily intake of dioxin-like compounds was 0.2 pg kg(-1) day(-1) in the HUA, which are below the WHO tolerable daily intake level. The results showed that the contribution to the toxic equivalency (TEQ) was dominated by PCB169, PCB105, and PCB81. FAU - Hong, Youwei AU - Hong Y AD - Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, 361021, People's Republic of China. AD - Ningbo Urban Environment Observation and Research Station-NUEORS, Chinese Academy of Sciences, Ningbo, 315800, People's Republic of China. AD - Department of Environmental Sciences, University of California, Riverside, CA, 92521, USA. FAU - Chen, Jinsheng AU - Chen J AD - Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, 361021, People's Republic of China. jschen@iue.ac.cn. AD - Ningbo Urban Environment Observation and Research Station-NUEORS, Chinese Academy of Sciences, Ningbo, 315800, People's Republic of China. jschen@iue.ac.cn. FAU - Zhang, Fuwang AU - Zhang F AD - Environmental Monitoring Center of Fujian, Fuzhou, 350003, China. FAU - Zhang, Han AU - Zhang H AD - Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, 361021, People's Republic of China. hzhang@iue.ac.cn. AD - Ningbo Urban Environment Observation and Research Station-NUEORS, Chinese Academy of Sciences, Ningbo, 315800, People's Republic of China. hzhang@iue.ac.cn. FAU - Xu, Lingling AU - Xu L AD - Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, 361021, People's Republic of China. AD - Ningbo Urban Environment Observation and Research Station-NUEORS, Chinese Academy of Sciences, Ningbo, 315800, People's Republic of China. FAU - Yin, Liqian AU - Yin L AD - Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, 361021, People's Republic of China. AD - Ningbo Urban Environment Observation and Research Station-NUEORS, Chinese Academy of Sciences, Ningbo, 315800, People's Republic of China. FAU - Chen, Yanting AU - Chen Y AD - Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, 361021, People's Republic of China. AD - Ningbo Urban Environment Observation and Research Station-NUEORS, Chinese Academy of Sciences, Ningbo, 315800, People's Republic of China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20150522 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Air Pollutants) RN - 0 (Vehicle Emissions) RN - 3417WMA06D (Benzo(a)pyrene) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Air Pollutants/*analysis MH - Benzo(a)pyrene/*analysis MH - China MH - Cities MH - Humans MH - Polychlorinated Biphenyls/*analysis MH - Risk Assessment MH - *Urbanization MH - Vehicle Emissions/analysis OTO - NOTNLM OT - Gas-particle distribution OT - PAHs OT - PCBs OT - Sources OT - Toxicological equivalent OT - Urbanization EDAT- 2015/05/23 06:00 MHDA- 2016/05/12 06:00 CRDT- 2015/05/22 06:00 PHST- 2015/01/21 00:00 [received] PHST- 2015/04/26 00:00 [accepted] PHST- 2015/05/22 06:00 [entrez] PHST- 2015/05/23 06:00 [pubmed] PHST- 2016/05/12 06:00 [medline] AID - 10.1007/s11356-015-4616-2 [pii] AID - 10.1007/s11356-015-4616-2 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2015 Oct;22(19):14919-31. doi: 10.1007/s11356-015-4616-2. Epub 2015 May 22.