PMID- 26104904 OWN - NLM STAT- MEDLINE DCOM- 20160617 LR - 20181202 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 22 IP - 21 DP - 2015 Nov TI - Permeable reactive barrier of coarse sand-supported zero valent iron for the removal of 2,4-dichlorophenol in groundwater. PG - 16889-96 LID - 10.1007/s11356-015-4912-x [doi] AB - In this study, coarse sand-supported zero valent iron (ZVI) composite was synthesized by adding sodium alginate to immobilize. Composite was detected by scanning electron microscope (SEM), X-ray diffraction (XRD), and X-ray fluorescence (XRF). SEM results showed that composite had core-shell structure and a wide porous distribution pattern. The synthesized composite was used for degradation of 2,4-dichlorophenol (2,4-DCP) contamination in groundwater. Experimental results demonstrated that degradation mechanism of 2,4-DCP using coarse sand-supported ZVI included adsorption, desorption, and dechlorination. 2,4-DCP adsorption was described as pseudo-second-order kinetic model. It was concluded that dechlorination was the key reaction pathway, ZVI and hydrogen are prime reductants in dechlorination of 2,4-DCP using ZVI. FAU - Gao, Weichun AU - Gao W AD - Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing, 100124, People's Republic of China. FAU - Zhang, Yongxiang AU - Zhang Y AD - Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing, 100124, People's Republic of China. yxzhang@bjut.edu.cn. FAU - Zhang, Xiaoye AU - Zhang X AD - Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing, 100124, People's Republic of China. FAU - Duan, Zhilong AU - Duan Z AD - Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing, 100124, People's Republic of China. FAU - Wang, Youhao AU - Wang Y AD - Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing, 100124, People's Republic of China. FAU - Qin, Can AU - Qin C AD - Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing, 100124, People's Republic of China. FAU - Hu, Xiao AU - Hu X AD - Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing, 100124, People's Republic of China. FAU - Wang, Hao AU - Wang H AD - Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing, 100124, People's Republic of China. FAU - Chang, Shan AU - Chang S AD - Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing, 100124, People's Republic of China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20150625 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Alginates) RN - 0 (Chlorophenols) RN - 0 (Hexuronic Acids) RN - 0 (Water Pollutants, Chemical) RN - 7631-86-9 (Silicon Dioxide) RN - 8A5D83Q4RW (Glucuronic Acid) RN - E1UOL152H7 (Iron) RN - R669TG1950 (2,4-dichlorophenol) SB - IM MH - Adsorption MH - Alginates/*chemistry MH - Chlorophenols/*isolation & purification MH - Glucuronic Acid/chemistry MH - Groundwater/*chemistry MH - Hexuronic Acids/chemistry MH - Iron/*chemistry MH - Kinetics MH - Microscopy, Electron, Scanning MH - Models, Theoretical MH - Silicon Dioxide/*chemistry MH - Surface Properties MH - Water Pollutants, Chemical/*isolation & purification MH - Water Purification/methods MH - X-Ray Diffraction OTO - NOTNLM OT - 2,4-dichlorophenol OT - Coarse sand OT - Dechlorination OT - Groundwater OT - Permeable reactive barrier OT - Zero valent iron EDAT- 2015/06/25 06:00 MHDA- 2016/06/18 06:00 CRDT- 2015/06/25 06:00 PHST- 2015/01/22 00:00 [received] PHST- 2015/06/16 00:00 [accepted] PHST- 2015/06/25 06:00 [entrez] PHST- 2015/06/25 06:00 [pubmed] PHST- 2016/06/18 06:00 [medline] AID - 10.1007/s11356-015-4912-x [pii] AID - 10.1007/s11356-015-4912-x [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2015 Nov;22(21):16889-96. doi: 10.1007/s11356-015-4912-x. Epub 2015 Jun 25.