PMID- 26162333 OWN - NLM STAT- MEDLINE DCOM- 20160627 LR - 20181202 IS - 1873-6424 (Electronic) IS - 0269-7491 (Linking) VI - 206 DP - 2015 Nov TI - Occurrence of organochlorine pesticides in the environmental matrices from King George Island, west Antarctica. PG - 142-9 LID - S0269-7491(15)00318-8 [pii] LID - 10.1016/j.envpol.2015.06.025 [doi] AB - Antarctica is considered as a final sink of many persistent organic pollutants (POPs). This work aims to investigate the levels, distributions and potential sources of organochlorine pesticides (OCPs) with HRGC/HRMS technique. Twenty-three OCPs were measured in various environmental matrices from King George Island, west Antarctica. The total concentrations (Sigma23OCPs) were at quite low levels, ranging 93.6-1260 pg g(-1) dry weight (dw) in soil and sediment, 223-1053 pg g(-1) dw in moss and 373-812 pg g(-1) dw in lichen. Hexachlorobenzene (HCB), dichloro-diphenyl-trichloroethane (DDT) and its metabolites (especially p,p'-DDE) and hexachlorocyclohexanes (HCHs) were the main contaminants in all samples. Lower alpha-HCH/gamma-HCH and higher p,p'-DDE/p,p'-DDT ratios compared with the technical products indicated long-range atmospheric transport (LRAT) of recent lindane and aged technical DDT. Significant dependence of many OCPs concentrations on total organic carbon (TOC) was observed. Apart from LRAT, local biotic activities could also contribute and influence the spatial distribution of the contaminants. CI - Copyright (c) 2015 Elsevier Ltd. All rights reserved. FAU - Zhang, Qinghua AU - Zhang Q AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; Institute of Environment and Health, Jianghan University, Wuhan 430056, China. Electronic address: qhzhang@rcees.ac.cn. FAU - Chen, Zhaojing AU - Chen Z AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Li, Yingming AU - Li Y AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Wang, Pu AU - Wang P AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Zhu, Chaofei AU - Zhu C AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Gao, Guanjun AU - Gao G AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Xiao, Ke AU - Xiao K AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Sun, Huizhong AU - Sun H AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Zheng, Shucheng AU - Zheng S AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Liang, Yong AU - Liang Y AD - Institute of Environment and Health, Jianghan University, Wuhan 430056, China; School of Medicine, Jianghan University, Wuhan 430056, China. FAU - Jiang, Guibin AU - Jiang G AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20150708 PL - England TA - Environ Pollut JT - Environmental pollution (Barking, Essex : 1987) JID - 8804476 RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticides) RN - 0 (Soil) RN - 0 (Soil Pollutants) RN - 319-84-6 (alpha-hexachlorocyclohexane) RN - 4M7FS82U08 (Dichlorodiphenyl Dichloroethylene) RN - 4Z87H0LKUY (Hexachlorobenzene) RN - 59NEE7PCAB (Hexachlorocyclohexane) SB - IM MH - Antarctic Regions MH - Bryopsida/metabolism MH - Dichlorodiphenyl Dichloroethylene/analysis/chemistry MH - Environmental Monitoring/methods MH - Geologic Sediments/chemistry MH - Hexachlorobenzene/analysis/chemistry MH - Hexachlorocyclohexane/analysis/chemistry MH - Humans MH - Hydrocarbons, Chlorinated/*analysis/chemistry/metabolism MH - Islands MH - Lichens/metabolism MH - Pesticides/*analysis/chemistry/metabolism MH - Soil/chemistry MH - Soil Pollutants/*analysis/chemistry/metabolism OTO - NOTNLM OT - Antarctica OT - HRGC/HRMS OT - Organochlorine pesticides OT - Soil OT - Vegetation EDAT- 2015/07/15 06:00 MHDA- 2016/06/28 06:00 CRDT- 2015/07/12 06:00 PHST- 2015/04/17 00:00 [received] PHST- 2015/06/16 00:00 [revised] PHST- 2015/06/21 00:00 [accepted] PHST- 2015/07/12 06:00 [entrez] PHST- 2015/07/15 06:00 [pubmed] PHST- 2016/06/28 06:00 [medline] AID - S0269-7491(15)00318-8 [pii] AID - 10.1016/j.envpol.2015.06.025 [doi] PST - ppublish SO - Environ Pollut. 2015 Nov;206:142-9. doi: 10.1016/j.envpol.2015.06.025. Epub 2015 Jul 8.