PMID- 26164912
OWN - NLM
STAT- MEDLINE
DCOM- 20150817
LR  - 20181202
IS  - 0250-3301 (Print)
IS  - 0250-3301 (Linking)
VI  - 36
IP  - 4
DP  - 2015 Apr
TI  - [Photolysis of Gaseous HNO3 on the alpha-Fe2O3 Films Under 308 nm UV Light].
PG  - 1359-64
AB  - Under 308 nm UV light, photolysis of HNO3 in the gas phase and on the alpha-Fe2O3 
      films was studied by using ultraviolet-visible spectrophotometer (UV-Vis), 
      Fourier transform infrared spectrometer (FTIR) combined with ion chromatography 
      (IC) technique. The effects of HNO3 initial concentration, relative humidity (RH) 
      and illumination time were systematically investigated. Results showed photolysis 
      of HNO3 could produce NO2 and NO in the gas phase and on the alpha-Fe2O3 films. With 
      the increase of reaction time and HNO3 initial concentration, the concentration 
      of NO2 and NO were all increased exponentially. NO2 and NO concentrations 
      produced from photolysis of HNO3 on alpha-Fe2O3 films were about 3.27 and 3.87 times 
      higher than those in gas phase, respectively. And NO2 concentration was about 2 
      times higher than that of NO whatever photolysis of HNO3 in gas phase or on 
      alpha-Fe2O3 films. HONO concentration increased in exponent regularity along with the 
      increase of RH. The yield of HONO increased from 0.023 to 0.087 when RH from 20% 
      increased to 90%. Surfaces effect played a leading role in photochemical reaction 
      of gaseous HNO3 on the alpha-Fe2O3 films.
FAU - Lu, Jun
AU  - Lu J
FAU - Sun, Yun-dong
AU  - Sun YD
FAU - Xie, Jing-jing
AU  - Xie JJ
FAU - Zhao, Jun
AU  - Zhao J
FAU - Zou, Jia-ji
AU  - Zou JJ
FAU - Zhu, Cheng-zhu
AU  - Zhu CZ
LA  - chi
PT  - Journal Article
PL  - China
TA  - Huan Jing Ke Xue
JT  - Huan jing ke xue= Huanjing kexue
JID - 8405344
RN  - 0 (Ferric Compounds)
RN  - 31C4KY9ESH (Nitric Oxide)
RN  - T2I5UM75DN (Nitrous Acid)
SB  - IM
MH  - Ferric Compounds/*chemistry
MH  - Nitric Oxide/chemistry
MH  - Nitrous Acid/*chemistry
MH  - Photolysis
MH  - *Ultraviolet Rays
EDAT- 2015/07/15 06:00
MHDA- 2015/08/19 06:00
CRDT- 2015/07/14 06:00
PHST- 2015/07/14 06:00 [entrez]
PHST- 2015/07/15 06:00 [pubmed]
PHST- 2015/08/19 06:00 [medline]
PST - ppublish
SO  - Huan Jing Ke Xue. 2015 Apr;36(4):1359-64.