PMID- 26212794
OWN - NLM
STAT- MEDLINE
DCOM- 20160516
LR  - 20150919
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 54
IP  - 39
DP  - 2015 Sep 21
TI  - Controllable Chemoselectivity in Visible-Light Photoredox Catalysis: Four Diverse 
      Aerobic Radical Cascade Reactions.
PG  - 11443-7
LID - 10.1002/anie.201505193 [doi]
AB  - Reported is the controllable selectivity syntheses of four distinct products from 
      the same starting materials by visible-light photoredox catalysis. By employing a 
      dicyanopyrazine-derived chromophore (DPZ) as photoredox catalyst, an aerobic 
      radical mechanism has been developed, and allows the reactions of 
      N-tetrahydroisoquinolines (THIQs) with N-itaconimides to through four different 
      pathways, including addition-cyclization, addition-elimination, 
      addition-coupling, and addition-protonation, with satisfactory chemoselectivity. 
      The current strategy provide straightforward access to four different but 
      valuable N-heterocyclic adducts in moderate to excellent yields.
CI  - (c) 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Liu, Xinfei
AU  - Liu X
AD  - Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province, 
      Henan University, Jinming Campus, Kaifeng, Henan, 475004 (P.R. China).
FAU - Ye, Xinyi
AU  - Ye X
AD  - Division of Chemistry and Biological Chemistry, Nanyang Technological University, 
      21 Nanyang Link, 637371 (Singapore). orgyxy@hotmail.com.
FAU - Bures, Filip
AU  - Bures F
AD  - Institute of Organic Chemistry and Technology, University of Pardubice, Faculty 
      of Chemical Technology, Studentska 573, Pardubice, 53210 (Czech Republic).
FAU - Liu, Hongjun
AU  - Liu H
AD  - Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province, 
      Henan University, Jinming Campus, Kaifeng, Henan, 475004 (P.R. China).
FAU - Jiang, Zhiyong
AU  - Jiang Z
AD  - Key Laboratory of Natural Medicine and Immuno-Engineering of Henan Province, 
      Henan University, Jinming Campus, Kaifeng, Henan, 475004 (P.R. China). 
      chmjzy@henu.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20150716
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
RN  - 0 (Free Radicals)
SB  - IM
MH  - Catalysis
MH  - Cycloaddition Reaction
MH  - Free Radicals/chemistry
MH  - *Light
MH  - Oxidation-Reduction
OTO - NOTNLM
OT  - heterocycles
OT  - photochemisty
OT  - radicals
OT  - reaction mechanisms
OT  - synthetic methods
EDAT- 2015/07/28 06:00
MHDA- 2016/05/18 06:00
CRDT- 2015/07/28 06:00
PHST- 2015/06/07 00:00 [received]
PHST- 2015/06/19 00:00 [revised]
PHST- 2015/07/28 06:00 [entrez]
PHST- 2015/07/28 06:00 [pubmed]
PHST- 2016/05/18 06:00 [medline]
AID - 10.1002/anie.201505193 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2015 Sep 21;54(39):11443-7. doi: 10.1002/anie.201505193. 
      Epub 2015 Jul 16.