PMID- 26322761 OWN - NLM STAT- MEDLINE DCOM- 20151106 LR - 20150901 IS - 1477-8920 (Print) IS - 1477-8920 (Linking) VI - 13 IP - 3 DP - 2015 Sep TI - Modeling benzene permeation through drinking water high density polyethylene (HDPE) pipes. PG - 758-72 LID - 10.2166/wh.2015.183 [doi] AB - Organic compounds such as benzene, toluene, ethyl benzene and o-, m-, and p-xylene from contaminated soil and groundwater may permeate through thermoplastic pipes which are used for the conveyance of drinking water in water distribution systems. In this study, permeation parameters of benzene in 25 mm (1 inch) standard inside dimension ratio (SIDR) 9 high density polyethylene (HDPE) pipes were estimated by fitting the measured data to a permeation model based on a combination of equilibrium partitioning and Fick's diffusion. For bulk concentrations between 6.0 and 67.5 mg/L in soil pore water, the concentration-dependent diffusion coefficients of benzene were found to range from 2.0x10(-9) to 2.8x10(-9) cm2/s while the solubility coefficient was determined to be 23.7. The simulated permeation curves of benzene for SIDR 9 and SIDR 7 series of HDPE pipes indicated that small diameter pipes were more vulnerable to permeation of benzene than large diameter pipes, and the breakthrough of benzene into the HDPE pipe was retarded and the corresponding permeation flux decreased with an increase of the pipe thickness. HDPE pipes exposed to an instantaneous plume exhibited distinguishable permeation characteristics from those exposed to a continuous source with a constant input. The properties of aquifer such as dispersion coefficients (DL) also influenced the permeation behavior of benzene through HDPE pipes. FAU - Mao, Feng AU - Mao F AD - Arizona Department of Environmental Quality, 1110 West Washington Street, Phoenix, AZ 85007, USA E-mail: mf8@azdeq.gov. FAU - Ong, Say Kee AU - Ong SK AD - Department of Civil, Construction and Environmental Engineering, Iowa State University, Ames, IA 50010, USA. FAU - Gaunt, James A AU - Gaunt JA AD - Department of Civil, Construction and Environmental Engineering, Iowa State University, Ames, IA 50010, USA. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - England TA - J Water Health JT - Journal of water and health JID - 101185420 RN - 0 (Drinking Water) RN - 9002-88-4 (Polyethylene) RN - J64922108F (Benzene) SB - IM MH - Benzene/*analysis/*chemistry MH - Diffusion MH - Drinking Water/standards MH - Kinetics MH - Models, Chemical MH - Permeability MH - Polyethylene/*chemistry MH - Water Quality/standards MH - *Water Supply EDAT- 2015/09/01 06:00 MHDA- 2015/11/07 06:00 CRDT- 2015/09/01 06:00 PHST- 2015/09/01 06:00 [entrez] PHST- 2015/09/01 06:00 [pubmed] PHST- 2015/11/07 06:00 [medline] AID - 10.2166/wh.2015.183 [doi] PST - ppublish SO - J Water Health. 2015 Sep;13(3):758-72. doi: 10.2166/wh.2015.183.