PMID- 26347171 OWN - NLM STAT- MEDLINE DCOM- 20160603 LR - 20150908 IS - 1873-4324 (Electronic) IS - 0003-2670 (Linking) VI - 890 DP - 2015 Aug 26 TI - A simple synthesis of nitrogen doped porous graphitic carbon: Electrochemical determination of paracetamol in presence of ascorbic acid and p-aminophenol. PG - 98-107 LID - S0003-2670(15)00905-8 [pii] LID - 10.1016/j.aca.2015.07.045 [doi] AB - Graphite paste electrode modified with nitrogen doped porous carbon (NDPC) is used for the detections of paracetamol (PCM), ascorbic acid (AA) and p-aminophenol (PAP) at relatively low concentration. NDPC is synthesized by direct carbonization of Zn(OAc)2 incorporated melamine-formaldehyde resin microsphere. The NDPC shows small pore diameters centered at 3.14 nm and 8.12 nm and has a pseudo graphitic structure with reasonable porous matrix. The lower limit of detections (S/N = 3) for PCM, AA, and PAP are found to be 30 nM, 720 nM and 10 nM respectively. Under optimized experimental condition, the linear ranges of determination for PCM and AA are 1-400 muM, 10-2700 muM respectively in mixture. Similarly for PCM and PAP mixture, the linear ranges of determination are found to be 1-90 muM. It is also used for the analysis of urine and pharmaceutical products with better sensitivity. CI - Copyright (c) 2015 Elsevier B.V. All rights reserved. FAU - Biswas, Sudip AU - Biswas S AD - Department of Instrumentation and Electronics Engineering, Jadavpur Universiy Salt Lake Campus, Kolkata 700098, India. FAU - Chakraborty, Dipanjan AU - Chakraborty D AD - Department of Instrumentation and Electronics Engineering, Jadavpur Universiy Salt Lake Campus, Kolkata 700098, India. FAU - Das, Rashmita AU - Das R AD - Department of Instrumentation and Electronics Engineering, Jadavpur Universiy Salt Lake Campus, Kolkata 700098, India. FAU - Bandyopadhyay, Rajib AU - Bandyopadhyay R AD - Department of Instrumentation and Electronics Engineering, Jadavpur Universiy Salt Lake Campus, Kolkata 700098, India. FAU - Pramanik, Panchanan AU - Pramanik P AD - Department of Basic Science, MCKV Institute of Engineering, Liluah, West Bengal 711204, India. Electronic address: pramanik1946@gmail.com. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20150812 PL - Netherlands TA - Anal Chim Acta JT - Analytica chimica acta JID - 0370534 RN - 0 (Aminophenols) RN - 362O9ITL9D (Acetaminophen) RN - 7782-42-5 (Graphite) RN - N762921K75 (Nitrogen) RN - PQ6CK8PD0R (Ascorbic Acid) RN - R7P8FRP05V (4-aminophenol) SB - IM MH - Acetaminophen/*analysis MH - Aminophenols/*chemistry MH - Ascorbic Acid/*chemistry MH - Catalysis MH - *Electrochemical Techniques MH - Electrodes MH - Graphite/*chemistry MH - Nitrogen/*chemistry MH - Oxidation-Reduction MH - Porosity MH - Reproducibility of Results MH - Spectroscopy, Fourier Transform Infrared MH - Spectrum Analysis, Raman OTO - NOTNLM OT - Electrochemical determination OT - Melamine-formaldehyde resin OT - Nitrogen doped porous carbon OT - Paracetamol OT - p-Aminophenol EDAT- 2015/09/09 06:00 MHDA- 2016/06/04 06:00 CRDT- 2015/09/09 06:00 PHST- 2015/05/14 00:00 [received] PHST- 2015/07/07 00:00 [revised] PHST- 2015/07/17 00:00 [accepted] PHST- 2015/09/09 06:00 [entrez] PHST- 2015/09/09 06:00 [pubmed] PHST- 2016/06/04 06:00 [medline] AID - S0003-2670(15)00905-8 [pii] AID - 10.1016/j.aca.2015.07.045 [doi] PST - ppublish SO - Anal Chim Acta. 2015 Aug 26;890:98-107. doi: 10.1016/j.aca.2015.07.045. Epub 2015 Aug 12.