PMID- 26352027
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20151124
LR  - 20150910
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 54
IP  - 38
DP  - 2015 Sep 14
TI  - Definitive molecular level characterization of defects in UiO-66 crystals.
PG  - 11162-7
LID - 10.1002/anie.201505461 [doi]
AB  - The identification and characterization of defects, on the molecular level, in 
      metal-organic frameworks (MOFs) remain a challenge. With the extensive use of 
      single-crystal X-ray diffraction (SXRD), the missing linker defects in the 
      zirconium-based MOF UiO-66, Zr6 O4 (OH)4 (C8 H4 O4 )6 , have been identified as 
      water molecules coordinated directly to the zirconium centers. Charge balancing 
      is achieved by hydroxide anions, which are hydrogen bonded within the pores of 
      the framework. Furthermore, the precise nature of the defects and their 
      concentration can be manipulated by altering the starting materials, synthesis 
      conditions, and post-synthetic modifications.
CI  - (c) 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Trickett, Christopher A
AU  - Trickett CA
AD  - Department of Chemistry, University of California-Berkeley, Materials Sciences 
      Division, Lawrence Berkeley National Laboratory, Kavli Energy Nanosciences 
      Institute at Berkeley, Center for Global Science at Berkeley, Berkeley, CA 94720 
      (USA).
FAU - Gagnon, Kevin J
AU  - Gagnon KJ
AD  - Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 
      (USA).
FAU - Lee, Seungkyu
AU  - Lee S
AD  - Department of Chemistry, University of California-Berkeley, Materials Sciences 
      Division, Lawrence Berkeley National Laboratory, Kavli Energy Nanosciences 
      Institute at Berkeley, Center for Global Science at Berkeley, Berkeley, CA 94720 
      (USA).
FAU - Gandara, Felipe
AU  - Gandara F
AD  - Department of New Architectures in Materials Chemistry, Materials Science 
      Institute of Madrid, Consejo Superior de Investigaciones Cientificas, Madrid 
      28049 (Spain).
FAU - Burgi, Hans-Beat
AU  - Burgi HB
AD  - Visiting Scholar at University of California - Berkeley, Institute of Chemistry, 
      University of Zurich, Winterthurestrasse, 190, 8057 Zurich (Switzerland).
FAU - Yaghi, Omar M
AU  - Yaghi OM
AD  - Department of Chemistry, University of California-Berkeley, Materials Sciences 
      Division, Lawrence Berkeley National Laboratory, Kavli Energy Nanosciences 
      Institute at Berkeley, Center for Global Science at Berkeley, Berkeley, CA 94720 
      (USA). yaghi@berkeley.edu.
AD  - King Abdulaziz City of Science and Technology, P.O. Box 6086, Riyadh 11442 (Saudi 
      Arabia). yaghi@berkeley.edu.
LA  - eng
PT  - Journal Article
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
OTO - NOTNLM
OT  - UiO-66
OT  - X-ray diffraction
OT  - metal-organic frameworks
OT  - single crystals
OT  - structure elucidation
EDAT- 2015/09/10 06:00
MHDA- 2015/09/10 06:01
CRDT- 2015/09/10 06:00
PHST- 2015/06/14 00:00 [received]
PHST- 2015/09/10 06:00 [entrez]
PHST- 2015/09/10 06:00 [pubmed]
PHST- 2015/09/10 06:01 [medline]
AID - 10.1002/anie.201505461 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2015 Sep 14;54(38):11162-7. doi: 10.1002/anie.201505461.