PMID- 26354692 OWN - NLM STAT- MEDLINE DCOM- 20160616 LR - 20170820 IS - 1001-0742 (Print) IS - 1001-0742 (Linking) VI - 35 DP - 2015 Sep 1 TI - High NO2/NOx emissions downstream of the catalytic diesel particulate filter: An influencing factor study. PG - 55-61 LID - S1001-0742(15)00209-0 [pii] LID - 10.1016/j.jes.2015.02.009 [doi] AB - Diesel vehicles are responsible for most of the traffic-related nitrogen oxide (NOx) emissions, including nitric oxide (NO) and nitrogen dioxide (NO2). The use of after-treatment devices increases the risk of high NO2/NOx emissions from diesel engines. In order to investigate the factors influencing NO2/NOx emissions, an emission experiment was carried out on a high pressure common-rail, turbocharged diesel engine with a catalytic diesel particulate filter (CDPF). NO2 was measured by a non-dispersive ultraviolet analyzer with raw exhaust sampling. The experimental results show that the NO2/NOx ratios downstream of the CDPF range around 20%-83%, which are significantly higher than those upstream of the CDPF. The exhaust temperature is a decisive factor influencing the NO2/NOx emissions. The maximum NO2/NOx emission appears at the exhaust temperature of 350 degrees C. The space velocity, engine-out PM/NOx ratio (mass based) and CO conversion ratio are secondary factors. At a constant exhaust temperature, the NO2/NOx emissions decreased with increasing space velocity and engine-out PM/NOx ratio. When the CO conversion ratios range from 80% to 90%, the NO2/NOx emissions remain at a high level. CI - Copyright (c) 2015. Published by Elsevier B.V. FAU - He, Chao AU - He C AD - School of Mechanical and Traffic Engineering, Southwest Forestry University, Kunming 650224, China. FAU - Li, Jiaqiang AU - Li J AD - School of Mechanical and Traffic Engineering, Southwest Forestry University, Kunming 650224, China; National Lab of Auto Performance and Emission Test, Beijing Institute of Technology, Beijing 10081, China. FAU - Ma, Zhilei AU - Ma Z AD - School of Mechanical and Traffic Engineering, Southwest Forestry University, Kunming 650224, China. FAU - Tan, Jianwei AU - Tan J AD - National Lab of Auto Performance and Emission Test, Beijing Institute of Technology, Beijing 10081, China. FAU - Zhao, Longqing AU - Zhao L AD - School of Mechanical and Traffic Engineering, Southwest Forestry University, Kunming 650224, China. Electronic address: hehesmile@gmail.com. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20150606 PL - Netherlands TA - J Environ Sci (China) JT - Journal of environmental sciences (China) JID - 100967627 RN - 0 (Air Pollutants) RN - 0 (Nitrogen Oxides) RN - 0 (Particulate Matter) RN - 0 (Vehicle Emissions) RN - 7U1EE4V452 (Carbon Monoxide) RN - S7G510RUBH (Nitrogen Dioxide) SB - IM MH - Air Pollutants/*analysis MH - Air Pollution/*prevention & control MH - Carbon Monoxide/chemistry MH - Environmental Monitoring MH - *Filtration MH - Kinetics MH - Nitrogen Dioxide/analysis MH - Nitrogen Oxides/*analysis MH - Particulate Matter/chemistry MH - Temperature MH - Vehicle Emissions/*analysis OTO - NOTNLM OT - Diesel engine OT - Diesel particulate filter OT - Exhaust temperature OT - Nitrogen dioxide OT - Space velocity EDAT- 2015/09/12 06:00 MHDA- 2016/06/17 06:00 CRDT- 2015/09/11 06:00 PHST- 2014/11/06 00:00 [received] PHST- 2015/02/06 00:00 [revised] PHST- 2015/02/09 00:00 [accepted] PHST- 2015/09/11 06:00 [entrez] PHST- 2015/09/12 06:00 [pubmed] PHST- 2016/06/17 06:00 [medline] AID - S1001-0742(15)00209-0 [pii] AID - 10.1016/j.jes.2015.02.009 [doi] PST - ppublish SO - J Environ Sci (China). 2015 Sep 1;35:55-61. doi: 10.1016/j.jes.2015.02.009. Epub 2015 Jun 6.