PMID- 26377443 OWN - NLM STAT- MEDLINE DCOM- 20160322 LR - 20181202 IS - 1361-6528 (Electronic) IS - 0957-4484 (Linking) VI - 26 IP - 40 DP - 2015 Oct 9 TI - Reduction of graphene oxide/alginate composite hydrogels for enhanced adsorption of hydrophobic compounds. PG - 405602 LID - 10.1088/0957-4484/26/40/405602 [doi] AB - Carbon-based materials, consisting of graphene oxide (GO) or reduced GO (rGO), possess unique abilities to interact with various molecules. In particular, rGO materials hold great promise for adsorption and delivery applications of hydrophobic molecules. However, conventional production and/or usage of rGO in aqueous solution often causes severe aggregation due to its low water solubility and thus difficulties in handling and applications. In our study, to prevent the severe aggregation of GO during reduction and to achieve a high adsorption capacity with hydrophobic compounds, GO/alginate composite hydrogels were first prepared and then reduced in an aqueous ascorbic acid solution at 37 degrees C. Adsorption studies with a model hydrophobic substance, rhodamine B, revealed that the reduced composite hydrogels are more highly absorbent than the unreduced hydrogels. In addition, the adsorption properties of the composite hydrogels, which are consequences of hydrophobic and ionic interactions, could be modulated by controlling the degree of reduction for the adsorption of different molecules. The composite hydrogels embedding rGO can be very useful in applications related to drug delivery, waste treatment, and biosensing. FAU - Kim, Semin AU - Kim S AD - School of Materials Science and Engineering, Gwangju Institute of Science and Technology, Gwangju 500-715, Korea. FAU - Yoo, Youngjae AU - Yoo Y FAU - Kim, Hanbit AU - Kim H FAU - Lee, Eunju AU - Lee E FAU - Lee, Jae Young AU - Lee JY LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20150917 PL - England TA - Nanotechnology JT - Nanotechnology JID - 101241272 RN - 0 (Alginates) RN - 0 (Hexuronic Acids) RN - 0 (Hydrogels) RN - 0 (Oxides) RN - 7782-42-5 (Graphite) RN - 8A5D83Q4RW (Glucuronic Acid) SB - IM MH - Adsorption MH - Alginates/*chemistry MH - Glucuronic Acid/chemistry MH - Graphite/*chemistry MH - Hexuronic Acids/chemistry MH - Hydrogels/*chemistry MH - Hydrophobic and Hydrophilic Interactions MH - Nanotechnology MH - Oxidation-Reduction MH - Oxides/*chemistry MH - Spectrum Analysis, Raman EDAT- 2015/09/18 06:00 MHDA- 2016/03/24 06:00 CRDT- 2015/09/18 06:00 PHST- 2015/09/18 06:00 [entrez] PHST- 2015/09/18 06:00 [pubmed] PHST- 2016/03/24 06:00 [medline] AID - 10.1088/0957-4484/26/40/405602 [doi] PST - ppublish SO - Nanotechnology. 2015 Oct 9;26(40):405602. doi: 10.1088/0957-4484/26/40/405602. Epub 2015 Sep 17.