PMID- 26408971 OWN - NLM STAT- MEDLINE DCOM- 20160902 LR - 20181202 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 144 DP - 2016 Feb TI - Residue levels and risk assessment of pesticides in nuts of China. PG - 645-51 LID - S0045-6535(15)30093-X [pii] LID - 10.1016/j.chemosphere.2015.09.008 [doi] AB - The pesticide residue levels of three nuts (chestnut, walnut, pinenut) collected from seven main producing areas of China were investigated. Twenty-nine pesticides, including organophosphates (OPs), organochlorines (OCs), pyrethroids (PYs) and two fungicides (triadimefon and buprofezin) were analyzed by gas chromatography (GC). Four OPs (acephate, dimethoate, chlorpyrifos and parathion-methyl) were found in 11.4% samples, with the concentrations of 19.0 microg kg(-1) to 74.0 microg kg(-1). Six OCs (DDT, HCH, endosulfan, quintozene, aldrin and dieldrin) were found in 18.2% samples, with the concentrations of 2.0 microg kg(-1) to 65.7 microg kg(-1). Among OCs, p,p-DDE and alpha-HCH were the dominant isomer for DDT and HCH. Five PYs (fenpropathrin, fenvalerate, cypermethrin, bifenthrin and cyhalothrin) were found in 15.9% samples, with the concentrations of 2.5 microg kg(-1) to 433.0 microg kg(-1). Fenpropathrin was the most frequently detected pesticide. In addition, triadimefon and buprofezin were detected only in two samples. For the tested nuts, 25.0% samples with multiple residues (containing more than two pesticides) were noted, even up to 9.1% samples with five pesticide residues. The residue of 15.9% samples was higher than the maximum residue limits (MRLs) of China. The short-term risks for the tested nuts were below 1.2%, and the highest long-term risk was 12.58%. The cumulative risk (cHI) for the tested pesticides were 8.43% (OPs), 0.42% (OCs), 12.82% (PYs) and 0.15% (fungicides), respectively. The total cHI was 21.82%. There was no significant health risk for consumers via nuts consumption. CI - Copyright (c) 2015 Elsevier Ltd. All rights reserved. FAU - Liu, Yihua AU - Liu Y AD - Research Institute of Subtropical Forestry, Chinese Academy of Forestry, Fuyang, 311400, China. FAU - Shen, Danyu AU - Shen D AD - Research Institute of Subtropical Forestry, Chinese Academy of Forestry, Fuyang, 311400, China. FAU - Li, Shiliang AU - Li S AD - Research Institute of Subtropical Forestry, Chinese Academy of Forestry, Fuyang, 311400, China. FAU - Ni, Zhanglin AU - Ni Z AD - Research Institute of Subtropical Forestry, Chinese Academy of Forestry, Fuyang, 311400, China. FAU - Ding, Ming AU - Ding M AD - Research Institute of Subtropical Forestry, Chinese Academy of Forestry, Fuyang, 311400, China. FAU - Ye, Caifen AU - Ye C AD - Research Institute of Subtropical Forestry, Chinese Academy of Forestry, Fuyang, 311400, China. FAU - Tang, Fubin AU - Tang F AD - Research Institute of Subtropical Forestry, Chinese Academy of Forestry, Fuyang, 311400, China. Electronic address: yalin_zj@163.com. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20150925 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Pesticide Residues) SB - IM MH - China MH - Food Contamination/*analysis MH - Nuts/*chemistry MH - Pesticide Residues/*analysis/toxicity MH - Risk Assessment OTO - NOTNLM OT - Food safety OT - Nut OT - Pesticide OT - Residue OT - Risk assessment EDAT- 2015/09/27 06:00 MHDA- 2016/09/03 06:00 CRDT- 2015/09/27 06:00 PHST- 2015/07/01 00:00 [received] PHST- 2015/09/01 00:00 [revised] PHST- 2015/09/02 00:00 [accepted] PHST- 2015/09/27 06:00 [entrez] PHST- 2015/09/27 06:00 [pubmed] PHST- 2016/09/03 06:00 [medline] AID - S0045-6535(15)30093-X [pii] AID - 10.1016/j.chemosphere.2015.09.008 [doi] PST - ppublish SO - Chemosphere. 2016 Feb;144:645-51. doi: 10.1016/j.chemosphere.2015.09.008. Epub 2015 Sep 25.