PMID- 26408981
OWN - NLM
STAT- MEDLINE
DCOM- 20160909
LR  - 20181202
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 144
DP  - 2016 Feb
TI  - Molecular entrapment of volatile organic compounds (VOCs) by electrospun 
      cyclodextrin nanofibers.
PG  - 736-44
LID - S0045-6535(15)30116-8 [pii]
LID - 10.1016/j.chemosphere.2015.09.029 [doi]
AB  - In this paper, we reported the molecular entrapment performance of 
      hydroxypropyl-beta-cyclodextrin (HPbetaCD) and hydroxypropyl-gamma-cyclodextrin 
      (HPgammaCD) electrospun nanofibers (NF) for two common volatile organic compounds 
      (VOCs); aniline and benzene. The encapsulation efficiency of CD samples were 
      investigated depending on the various factors such as; CD form (NF and powder), 
      electrospinning solvent (DMF and water), CD (HPbetaCD and HPgammaCD) and VOCs (aniline 
      and benzene) types. BET analysis indicated that, electrospun CD NF have higher 
      surface area compared to their powder form. In addition DMA measurement provided 
      information about the mechanical properties of CD NF. The encapsulation 
      capability of CD NF and CD powder was investigated by (1)H-NMR and HPLC 
      techniques. The observed results suggested that, CD NF can entrap higher amount 
      of VOCs from surroundings compared to their powder forms. Besides, molecular 
      entrapment efficiency of CD NF also depends on CD, solvent and VOCs types. The 
      inclusion complexation between CD and VOCs was determined by using TGA technique, 
      from the higher decomposition temperature of VOCs. Finally, our results were 
      fortified by the modeling studies which indicated the complexation efficiency 
      variations between CD and VOC types. Here, the inclusion complexation ability of 
      CD molecules was combined with very high surface area and versatile features of 
      CD NF. So these findings revealed that, electrospun CD NF can serve as useful 
      filtering material for air  fi ltration purposes due to their molecular entrapment 
      capability of VOCs.
CI  - Copyright (c) 2015 Elsevier Ltd. All rights reserved.
FAU - Celebioglu, Asli
AU  - Celebioglu A
AD  - Institute of Materials Science & Nanotechnology, Bilkent University, Ankara, 
      06800, Turkey; UNAM-National Nanotechnology Research Center, Bilkent University, 
      Ankara, 06800, Turkey.
FAU - Sen, Huseyin Sener
AU  - Sen HS
AD  - UNAM-National Nanotechnology Research Center, Bilkent University, Ankara, 06800, 
      Turkey.
FAU - Durgun, Engin
AU  - Durgun E
AD  - Institute of Materials Science & Nanotechnology, Bilkent University, Ankara, 
      06800, Turkey; UNAM-National Nanotechnology Research Center, Bilkent University, 
      Ankara, 06800, Turkey.
FAU - Uyar, Tamer
AU  - Uyar T
AD  - Institute of Materials Science & Nanotechnology, Bilkent University, Ankara, 
      06800, Turkey; UNAM-National Nanotechnology Research Center, Bilkent University, 
      Ankara, 06800, Turkey. Electronic address: tamer@unam.bilkent.edu.tr.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20150925
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Air Pollutants)
RN  - 0 (Aniline Compounds)
RN  - 0 (beta-Cyclodextrins)
RN  - 0 (gamma-Cyclodextrins)
RN  - 0 (hydroxypropyl-gamma-cyclodextrin)
RN  - 1I96OHX6EK (2-Hydroxypropyl-beta-cyclodextrin)
RN  - J64922108F (Benzene)
RN  - SIR7XX2F1K (aniline)
SB  - IM
MH  - 2-Hydroxypropyl-beta-cyclodextrin
MH  - Air Pollutants/*chemistry/isolation & purification
MH  - Aniline Compounds/*chemistry/isolation & purification
MH  - Benzene/*chemistry/isolation & purification
MH  - *Electricity
MH  - Nanofibers/*chemistry
MH  - beta-Cyclodextrins/*chemistry
MH  - gamma-Cyclodextrins/*chemistry
OTO - NOTNLM
OT  - Cyclodextrin
OT  - Electrospinning
OT  - Molecular filtration
OT  - Nanofibers
OT  - Volatile organic compounds
EDAT- 2015/09/27 06:00
MHDA- 2016/09/10 06:00
CRDT- 2015/09/27 06:00
PHST- 2015/03/13 00:00 [received]
PHST- 2015/07/21 00:00 [revised]
PHST- 2015/09/06 00:00 [accepted]
PHST- 2015/09/27 06:00 [entrez]
PHST- 2015/09/27 06:00 [pubmed]
PHST- 2016/09/10 06:00 [medline]
AID - S0045-6535(15)30116-8 [pii]
AID - 10.1016/j.chemosphere.2015.09.029 [doi]
PST - ppublish
SO  - Chemosphere. 2016 Feb;144:736-44. doi: 10.1016/j.chemosphere.2015.09.029. Epub 
      2015 Sep 25.