PMID- 26426436
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20160408
LR  - 20151217
IS  - 1364-5498 (Electronic)
IS  - 1359-6640 (Linking)
VI  - 185
DP  - 2015
TI  - Synthesis and strong photooxidation power of a supramolecular hybrid comprising a 
      polyoxometalate and Ru(II) polypyridyl complex with zinc(II).
PG  - 171-85
LID - 10.1039/c5fd00080g [doi]
AB  - A novel method for constructing supramolecular hybrids composed of 
      polyoxometalates and photofunctional metal complexes was developed. A Ru(II) 
      complex with phosphonate groups (RuP) strongly interacted with Zn(II) to afford a 
      2 : 1 trinuclear metal complex ([(RuP)2Zn](3+)). In dimethylsulfoxide, 
      [(RuP)2Zn](3+) strongly interacted with a Keggin-type heteropolyoxometalate 
      (Si-WPOM) to form a 1 : 1 hybrid ([(RuP)2Zn]-POM). Irradiation of [(RuP)2Zn]-POM 
      in the presence of diethanolamine caused rapid accumulation of the one-electron 
      reduced hybrid with a quantum yield of 0.99.
FAU - Ohashi, Kenji
AU  - Ohashi K
AD  - Department of Chemistry, Graduate School of Science and Engineering, Tokyo 
      Institute of Technology, Ookayama 2-12-1-NE-1, Meguro-ku, Tokyo 152-8551, Japan. 
      ishitani@chem.titech.ac.jp.
FAU - Takeda, Hiroyuki
AU  - Takeda H
FAU - Koike, Kazuhide
AU  - Koike K
FAU - Ishitani, Osamu
AU  - Ishitani O
LA  - eng
PT  - Journal Article
DEP - 20151001
PL  - England
TA  - Faraday Discuss
JT  - Faraday discussions
JID - 9212301
EDAT- 2015/10/02 06:00
MHDA- 2015/10/02 06:01
CRDT- 2015/10/02 06:00
PHST- 2015/10/02 06:00 [entrez]
PHST- 2015/10/02 06:00 [pubmed]
PHST- 2015/10/02 06:01 [medline]
AID - 10.1039/c5fd00080g [doi]
PST - ppublish
SO  - Faraday Discuss. 2015;185:171-85. doi: 10.1039/c5fd00080g. Epub 2015 Oct 1.