PMID- 26471347
OWN - NLM
STAT- MEDLINE
DCOM- 20160627
LR  - 20151103
IS  - 1520-5827 (Electronic)
IS  - 0743-7463 (Linking)
VI  - 31
IP  - 43
DP  - 2015 Nov 3
TI  - Simultaneous Formation of a Self-Wrinkled Surface and Silver Nanoparticles on a 
      Functional Photocuring Coating.
PG  - 11800-8
LID - 10.1021/acs.langmuir.5b03484 [doi]
AB  - Bioinspired functional surface with micro/nanostructures are particularly 
      attractive because of the potential for outstanding characteristics, such as 
      self-cleaning, self-replenishing and antibiosis. Here, we presented a facile 
      approach to fabricate a functional photocuring coating with both a self-wrinkling 
      patterned surface and incorporated silver nanoparticles (Ag NPs). Fluorinated 
      polymeric photoinitiator (FPPI) and silver precursor (TFAAg) can self-assemble 
      together on the air/acrylate interface to form a top layer of photocuring liquid 
      resin. Under UV irradiation, a wrinkled pattern was formed as a result of the 
      mismatch in shrinkage caused by photopolymerization between the top layer and the 
      bulk layer. Simultaneously, Ag NPs with sizes of 15 +/- 8 nm in diameter were in 
      situ generated in the photocuring coating through the photoreduction of TFAAg. 
      Their number density is higher in the top layer than in the bulk. Scanning 
      electron microscope (SEM) and atomic force microscope (AFM) measurements revealed 
      that the characteristic wavelength (lambda) and amplitude (A) of the wrinkled 
      morphology increased with growing concentration of FPPI, and that the generation 
      of Ag NPs led to the wrinkle-to-fold transition. Furthermore, the obtained 
      functional coatings possess a low surface energy and self-replenishing and 
      antibiosis capabilities as a result of the synergistic effect of the wrinkled 
      surface covered by FPPI and Ag NPs.
FAU - Lin, Hongbo
AU  - Lin H
AD  - School of Chemistry & Chemical Engineering, State Key Laboratory for Metal Matrix 
      Composite Materials, Shanghai Jiao Tong University , Shanghai 200240, People's 
      Republic of China.
FAU - Wang, Yuanlong
AU  - Wang Y
AD  - State Key Laboratory of Dairy Biotechnology, Dairy Research Institute, Bright 
      Dairy & Food Co., Ltd. , Shanghai 200436, People's Republic of China.
FAU - Gan, Yanchang
AU  - Gan Y
AD  - School of Chemistry & Chemical Engineering, State Key Laboratory for Metal Matrix 
      Composite Materials, Shanghai Jiao Tong University , Shanghai 200240, People's 
      Republic of China.
FAU - Hou, Honghao
AU  - Hou H
AD  - School of Chemistry & Chemical Engineering, State Key Laboratory for Metal Matrix 
      Composite Materials, Shanghai Jiao Tong University , Shanghai 200240, People's 
      Republic of China.
FAU - Yin, Jie
AU  - Yin J
AD  - School of Chemistry & Chemical Engineering, State Key Laboratory for Metal Matrix 
      Composite Materials, Shanghai Jiao Tong University , Shanghai 200240, People's 
      Republic of China.
FAU - Jiang, Xuesong
AU  - Jiang X
AD  - School of Chemistry & Chemical Engineering, State Key Laboratory for Metal Matrix 
      Composite Materials, Shanghai Jiao Tong University , Shanghai 200240, People's 
      Republic of China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20151022
PL  - United States
TA  - Langmuir
JT  - Langmuir : the ACS journal of surfaces and colloids
JID - 9882736
RN  - 3M4G523W1G (Silver)
SB  - IM
MH  - *Light
MH  - Metal Nanoparticles/*chemistry
MH  - Silver/*chemistry
MH  - Surface Properties
EDAT- 2015/10/17 06:00
MHDA- 2016/06/28 06:00
CRDT- 2015/10/17 06:00
PHST- 2015/10/17 06:00 [entrez]
PHST- 2015/10/17 06:00 [pubmed]
PHST- 2016/06/28 06:00 [medline]
AID - 10.1021/acs.langmuir.5b03484 [doi]
PST - ppublish
SO  - Langmuir. 2015 Nov 3;31(43):11800-8. doi: 10.1021/acs.langmuir.5b03484. Epub 2015 
      Oct 22.