PMID- 26493991
OWN - NLM
STAT- MEDLINE
DCOM- 20160520
LR  - 20190111
IS  - 1573-2959 (Electronic)
IS  - 0167-6369 (Linking)
VI  - 187
IP  - 11
DP  - 2015 Nov
TI  - Dissipation, terminal residues and risk assessment of fluopicolide and its 
      metabolite in cucumber under field conditions.
PG  - 698
LID - 10.1007/s10661-015-4924-5 [doi]
AB  - In this study, the dissipation, terminal residue levels, and risk assessment of 
      fluopicolide and its metabolite (2,6-dichlorobenzamide) in cucumber and soil 
      under field conditions were investigated. An analytical method for the 
      simultaneous quantification of fluopicolide and its metabolite in cucumber and 
      soil using gas chromatography coupled with electron capture detection (GC-ECD) 
      was developed. Recoveries were between 78 and 111%, with relative standard 
      deviations (RSDs) from 1.6 to 10.2% at different spiked levels (0.01, 0.025, 0.5, 
      and 2 mg kg(-1)). The limit of quantification (LOQ) was 0.01 mg kg(-1). 
      Fluopicolide exhibited half-lives ranging from 2.0 to 3.3 days and 35 to 63 days, 
      in cucumber and soil under field ecosystem, respectively. The results suggested 
      that the degradation of fluopicolide to 2,6-dichlorobenzamide was quite limited. 
      During harvest, the terminal residues of fluopicolide and its metabolite were 
      both below 0.13 mg kg(-1), which were lower than the established temporary 
      maximum residue limits (MRLs), 0.5 mg kg(-1). The risk quotients (RQs) ranged 
      from 0.0033 to 0.0078, which showed low risk for different groups of people in 
      China. The present study may provide guidance on reasonable use of this pesticide 
      and serve as a reference for establishment official MRLs in China.
FAU - Shi, Kaiwei
AU  - Shi K
AD  - College of Science, China Agricultural University, Beijing, 100193, China.
AD  - State Key Laboratory of Integrated Management of Pest Insects and Rodents, 
      Institute of Zoology, Chinese Academy of Sciences, Beijing, 100101, China.
FAU - Li, Wei
AU  - Li W
AD  - State Key Laboratory of Integrated Management of Pest Insects and Rodents, 
      Institute of Zoology, Chinese Academy of Sciences, Beijing, 100101, China.
FAU - Yuan, Longfei
AU  - Yuan L
AD  - State Key Laboratory of Integrated Management of Pest Insects and Rodents, 
      Institute of Zoology, Chinese Academy of Sciences, Beijing, 100101, China.
FAU - Li, Li
AU  - Li L
AD  - State Key Laboratory of Integrated Management of Pest Insects and Rodents, 
      Institute of Zoology, Chinese Academy of Sciences, Beijing, 100101, China. 
      lili2008@ioz.ac.cn.
FAU - Liu, Fengmao
AU  - Liu F
AD  - College of Science, China Agricultural University, Beijing, 100193, China. 
      liufengmao@cau.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20151022
PL  - Netherlands
TA  - Environ Monit Assess
JT  - Environmental monitoring and assessment
JID - 8508350
RN  - 0 (Benzamides)
RN  - 0 (Pesticide Residues)
RN  - 0 (Soil)
RN  - 0 (Soil Pollutants)
RN  - 6TRO75M67P (fluopicolide)
RN  - E9JWF529EB (2,6-dichlorobenzamide)
SB  - IM
MH  - Benzamides/*analysis
MH  - China
MH  - Chromatography, Gas
MH  - Cucumis sativus/*metabolism
MH  - Ecosystem
MH  - *Environmental Monitoring
MH  - Half-Life
MH  - Pesticide Residues/*analysis
MH  - Risk Assessment
MH  - Soil/chemistry
MH  - Soil Pollutants/*analysis
OTO - NOTNLM
OT  - Cucumber
OT  - Fluopicolide
OT  - Metabolite
OT  - Residue
OT  - Risk assessment
EDAT- 2015/10/27 06:00
MHDA- 2016/05/21 06:00
CRDT- 2015/10/24 06:00
PHST- 2015/06/23 00:00 [received]
PHST- 2015/10/13 00:00 [accepted]
PHST- 2015/10/24 06:00 [entrez]
PHST- 2015/10/27 06:00 [pubmed]
PHST- 2016/05/21 06:00 [medline]
AID - 10.1007/s10661-015-4924-5 [pii]
AID - 10.1007/s10661-015-4924-5 [doi]
PST - ppublish
SO  - Environ Monit Assess. 2015 Nov;187(11):698. doi: 10.1007/s10661-015-4924-5. Epub 
      2015 Oct 22.