PMID- 26505766 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20160126 LR - 20151028 IS - 1096-9888 (Electronic) IS - 1076-5174 (Linking) VI - 50 IP - 11 DP - 2015 Nov TI - Evaluation of ice-tea quality by DART-TOF/MS. PG - 1214-21 LID - 10.1002/jms.3639 [doi] AB - DART (Direct Analysis in Real Time) coupled with Time-of-Flight Mass Spectrometry (TOF/MS) has been used for analyses of ice-teas. The article focuses on quality and authenticity of ice-teas as one of the most important tea-based products on the market. Twenty-one samples of ice-teas (black and green) were analysed. Selected compounds of ice-teas were determined: theobromine, caffeine, total phenolic compounds, total soluble solids, total amino acid concentration, preservatives and saccharides were determined. Fingerprints of DART-TOF/MS spectra were used for comprehensive assessment of the ice-tea samples. The DART-TOF/MS method was used for monitoring the following compounds: citric acid, caffeine, saccharides, artificial sweeteners (saccharin, acesulphame K), and preservatives (sorbic and benzoic acid), phosphoric acid and phenolic compounds. The measured data were subjected to a principal components analysis. The HPLC and DART-TOF/MS methods were compared in terms of determination of selected compounds (caffeine, benzoic acid, sorbic acid and saccharides) in the ice-teas. The DART-TOF/MS technique seems to be a suitable method for fast screening, testing quality and authenticity of tea-based products. CI - Copyright (c) 2015 John Wiley & Sons, Ltd. FAU - Rajchl, Ales AU - Rajchl A AD - Department of Food Preservation, University of Chemistry and Technology Prague, Technicka 5, 160 28, Prague 6, Czech Republic. FAU - Prchalova, Jana AU - Prchalova J AD - Department of Food Preservation, University of Chemistry and Technology Prague, Technicka 5, 160 28, Prague 6, Czech Republic. FAU - Kruzik, Vojtech AU - Kruzik V AD - Department of Food Preservation, University of Chemistry and Technology Prague, Technicka 5, 160 28, Prague 6, Czech Republic. FAU - Sevcik, Rudolf AU - Sevcik R AD - Department of Food Preservation, University of Chemistry and Technology Prague, Technicka 5, 160 28, Prague 6, Czech Republic. FAU - Cizkova, Helena AU - Cizkova H AD - Department of Food Preservation, University of Chemistry and Technology Prague, Technicka 5, 160 28, Prague 6, Czech Republic. LA - eng PT - Journal Article PL - England TA - J Mass Spectrom JT - Journal of mass spectrometry : JMS JID - 9504818 OTO - NOTNLM OT - DART OT - PCA analysis OT - TOF OT - ice-tea OT - quality EDAT- 2015/10/28 06:00 MHDA- 2015/10/28 06:01 CRDT- 2015/10/28 06:00 PHST- 2015/06/18 00:00 [received] PHST- 2015/08/03 00:00 [revised] PHST- 2015/08/05 00:00 [accepted] PHST- 2015/10/28 06:00 [entrez] PHST- 2015/10/28 06:00 [pubmed] PHST- 2015/10/28 06:01 [medline] AID - 10.1002/jms.3639 [doi] PST - ppublish SO - J Mass Spectrom. 2015 Nov;50(11):1214-21. doi: 10.1002/jms.3639.