PMID- 26539705 OWN - NLM STAT- MEDLINE DCOM- 20160912 LR - 20181202 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 144 DP - 2016 Feb TI - Historical deposition of persistent organic pollutants in Lake Victoria and two alpine equatorial lakes from East Africa: Insights into atmospheric deposition from sedimentation profiles. PG - 1815-22 LID - S0045-6535(15)30256-3 [pii] LID - 10.1016/j.chemosphere.2015.10.061 [doi] AB - Information on historical deposition of persistent organic pollutants (POPs) for African lakes is very limited. We investigated historical deposition trends and sources of POPs in sediment cores from Lakes Victoria (SC1), Bujuku (Buju2) and Mahoma (Maho2). The latter two lakes are situated in the Rwenzori mountain range in western Uganda. SC1 was taken from a central depositional area within the Ugandan part of the lake. Profiles in Buju2 and Maho2 were used as a reference for historical atmospheric deposition. For the post-1940 sediment deposits in SC1, average focusing factor-adjusted fluxes (FFFs) of SigmaDDTs, polychlorinated biphenyls (SigmaPCBs), hexachlorocyclohexanes (SigmaHCHs) and chlordanes (SigmaCHLs) were 390, 230, 210 and 120 ng m(-2) yr(-1). Higher fluxes of SigmaDDTs, SigmaPCBs, and SigmaCHLs were observed in Buju2 and Maho2. The average FFF of HCB in Buju2 was the highest while the values for Maho2 and SC1 were similar. The endosulfan FFFs in SC1 were lower than in the alpine lake cores. Generally, Buju2 was a better reference for historical atmospheric deposition of POPs than Maho2 probably due to distortion of the latter's profile by Lake Mahoma's forested catchment. Profiles of p,p'-DDE, SigmaCHLs and HCB in SC1 were consistent with atmospheric deposition while profiles of PCBs and HCHs were indicative of particle-bound loadings from additional sources. Profiles of endosulfans, DDTs, and chlordanes were consistent with influence of other factors such as anoxia, and dilution. Further studies of spatial resolution of historical deposition, especially in near-shore deposition areas of the lake are recommended. CI - Copyright (c) 2015 Elsevier Ltd. All rights reserved. FAU - Arinaitwe, Kenneth AU - Arinaitwe K AD - Chemistry Department, Makerere University, Kampala, Uganda. Electronic address: ken.arina@gmail.com. FAU - Rose, Neil L AU - Rose NL AD - Environmental Change Research Centre, University College London, London, UK. FAU - Muir, Derek C G AU - Muir DC AD - Aquatic Contaminants Research Division, Environment Canada, Burlington, ON, Canada. FAU - Kiremire, Bernard T AU - Kiremire BT AD - Chemistry Department, Makerere University, Kampala, Uganda. FAU - Balirwa, John S AU - Balirwa JS AD - National Fisheries Resources Research Institute (NaFIRRI), Jinja, Uganda. FAU - Teixeira, Camilla AU - Teixeira C AD - Aquatic Contaminants Research Division, Environment Canada, Burlington, ON, Canada. LA - eng PT - Historical Article PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20151111 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Water Pollutants, Chemical) RN - OKA6A6ZD4K (Endosulfan) SB - IM MH - Africa, Eastern MH - Endosulfan/*analysis/history MH - Environmental Monitoring/history MH - History, 20th Century MH - History, 21st Century MH - Hydrocarbons, Chlorinated/*analysis/history MH - Lakes/*analysis MH - Water Pollutants, Chemical/*analysis/history OTO - NOTNLM OT - Atmospheric deposition OT - East Africa OT - Lake Victoria OT - Mountain lakes OT - Persistent organic pollutant OT - Sedimentation EDAT- 2015/11/06 06:00 MHDA- 2016/09/13 06:00 CRDT- 2015/11/06 06:00 PHST- 2015/06/03 00:00 [received] PHST- 2015/10/11 00:00 [revised] PHST- 2015/10/14 00:00 [accepted] PHST- 2015/11/06 06:00 [entrez] PHST- 2015/11/06 06:00 [pubmed] PHST- 2016/09/13 06:00 [medline] AID - S0045-6535(15)30256-3 [pii] AID - 10.1016/j.chemosphere.2015.10.061 [doi] PST - ppublish SO - Chemosphere. 2016 Feb;144:1815-22. doi: 10.1016/j.chemosphere.2015.10.061. Epub 2015 Nov 11.