PMID- 26590145
OWN - NLM
STAT- MEDLINE
DCOM- 20160623
LR  - 20181202
IS  - 1573-2959 (Electronic)
IS  - 0167-6369 (Linking)
VI  - 187
IP  - 12
DP  - 2015 Dec
TI  - Dissipation kinetics of emamectin benzoate and lufenuron residues in cabbage 
      grown under field conditions.
PG  - 765
LID - 10.1007/s10661-015-4989-1 [doi]
AB  - Residue analysis of emamectin benzoate and lufenuron in cabbage matrices and soil 
      was developed using a quick, easy, cheap, effective, rugged, and safe (QuEChERS) 
      method and ultra high-performance liquid chromatography tandem mass spectrometry 
      (UPLC-MS/MS). The samples were extracted with 1% acetic acid in acetonitrile 
      (v/v) or 1% acetic acid in acetonitrile/water (5:1, v/v) and cleaned up by 
      dispersive solid-phase extraction. Mean recoveries and relative standard 
      deviations (RSDs) in all samples ranged 87.8-100.0 % and 3.6-12.6% for emamectin 
      benzoate and 87.8-104.8 % and 6.2-11.5% for lufenuron, respectively. The 
      validated method was used to evaluate the dissipation rate of emamectin benzoate 
      and lufenuron in cabbage and soil as well as the residual levels in harvested 
      cabbage and soil at different preharvest intervals (PHI). The half-lives of 
      emamectin benzoate and lufenuron were 1.08-2.70 and 1.74-5.04 days in cabbage, 
      and 1.42-4.01 and 0.94-6.18 days in soil, respectively. The terminal residues 
      were below the China maximum residue limits (MRLs) at 3 days for emamectin 
      benzoate (0.1 mg kg(-1)) and European Union MRLs at 5 days for lufenuron (0.5 mg 
      kg(-1)), which suggested that 5 days could be recommended as the PHI for the 
      commercial formulation of emamectin benzoate and lufenuron application in the 
      Chinese cabbage field.
FAU - Dong, Bizhang
AU  - Dong B
AD  - Lab of Pesticide Residues and Environmental Toxicology, School of Chemistry and 
      Biological Engineering, University of Science and Technology Beijing, Beijing, 
      100083, People's Republic of China.
FAU - Zhao, Qing
AU  - Zhao Q
AD  - Lab of Pesticide Residues and Environmental Toxicology, School of Chemistry and 
      Biological Engineering, University of Science and Technology Beijing, Beijing, 
      100083, People's Republic of China.
FAU - Hu, Jiye
AU  - Hu J
AD  - Lab of Pesticide Residues and Environmental Toxicology, School of Chemistry and 
      Biological Engineering, University of Science and Technology Beijing, Beijing, 
      100083, People's Republic of China. jyhu@ustb.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20151120
PL  - Netherlands
TA  - Environ Monit Assess
JT  - Environmental monitoring and assessment
JID - 8508350
RN  - 0 (Acetonitriles)
RN  - 0 (Benzamides)
RN  - 0 (Pesticide Residues)
RN  - 0 (Plant Extracts)
RN  - 0 (Soil)
RN  - 0 (Soil Pollutants)
RN  - 1R754M4918 (fluphenacur)
RN  - 70288-86-7 (Ivermectin)
RN  - HVM3G4A01W (emamectin benzoate)
RN  - Q40Q9N063P (Acetic Acid)
RN  - Z072SB282N (acetonitrile)
SB  - IM
MH  - Acetic Acid/chemistry
MH  - Acetonitriles/chemistry
MH  - Benzamides/*analysis
MH  - Brassica/*chemistry
MH  - Calibration
MH  - China
MH  - Chromatography, Liquid
MH  - Environmental Monitoring/*methods
MH  - Half-Life
MH  - Ivermectin/*analogs & derivatives/analysis
MH  - Kinetics
MH  - Pesticide Residues/*analysis
MH  - Plant Extracts/*chemistry
MH  - Soil/chemistry
MH  - Soil Pollutants/analysis
MH  - Solid Phase Extraction
MH  - Tandem Mass Spectrometry
OTO - NOTNLM
OT  - Cabbage
OT  - Dissipation
OT  - Emamectin benzoate
OT  - Lufenuron
OT  - Residues
EDAT- 2015/11/22 06:00
MHDA- 2016/06/24 06:00
CRDT- 2015/11/22 06:00
PHST- 2015/05/25 00:00 [received]
PHST- 2015/11/12 00:00 [accepted]
PHST- 2015/11/22 06:00 [entrez]
PHST- 2015/11/22 06:00 [pubmed]
PHST- 2016/06/24 06:00 [medline]
AID - 10.1007/s10661-015-4989-1 [pii]
AID - 10.1007/s10661-015-4989-1 [doi]
PST - ppublish
SO  - Environ Monit Assess. 2015 Dec;187(12):765. doi: 10.1007/s10661-015-4989-1. Epub 
      2015 Nov 20.