PMID- 26592590
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20160906
LR  - 20151123
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 147
DP  - 2016 Jan 15
TI  - Development of a novel, fast, sensitive method for chromium speciation in 
      wastewater based on an organic polymer as solid phase extraction material 
      combined with HPLC-ICP-MS.
PG  - 155-61
LID - S0039-9140(15)30338-6 [pii]
LID - 10.1016/j.talanta.2015.09.047 [doi]
AB  - Speciation analysis of inorganic chromium in wastewater is of great significance 
      for the monitoring of environmental pollution. In this work, 
      N,N-bis(2-aminoethyl)ethane-1,2-diamine functionalized poly(chloromethyl 
      styrene-co-styrene) was synthesized, characterized and used as the adsorbent to 
      preconcentrate chromium species in environmental waters by on line solid-phase 
      extraction (SPE). The trace speciation analysis of Cr(III) and Cr(VI) in 
      wastewater has been used by short-column high-performance liquid chromatography 
      hyphenated to inductively coupled plasma spectrometry (HPLC-ICP-MS) after on-line 
      SPE. Cr(III) and Cr(VI) have been adsorbed on the anion exchange column after 
      transforming the cationic Cr(III) to an anionic [Cr(III)-EDTA](-) complex devoid 
      of re-dox reagent, and then eluted rapidly (within seconds) with a very low 
      concentration of tetrabutylammonium hydroxide (TBAH) solution. This method 
      provides a reliable on-line preconcentration method and detection coupled 
      technique. Under the optimized conditions, high enrichment factors have been 
      obtained for Cr(VI) and [Cr(III)-EDTA](-) with 30mL sample solution up to 105 and 
      128, respectively. The low detection limits of 0.0068ng mL(-1) and 0.0041ng 
      mL(-1), with the relative standard deviations (RSDs) of 4.3% and 3.6% were 
      obtained for Cr(VI) and [Cr(III)-EDTA](-), respectively. The developed method was 
      validated by analyzing Certified Reference Materials GSBZ50027-94, and the spike 
      tests were also performed. At the same time, thanks to the merit of simple 
      operation, rapid adsorption/desorption dynamics, high enrichment and low LODs, 
      the established method was applied to analyze three wastewater samples from 
      different discharge port.
CI  - Copyright (c) 2015 Elsevier B.V. All rights reserved.
FAU - Jia, Xiaoyu
AU  - Jia X
AD  - Key Lab of Urban Environment and Health, Institute of Urban Environment, Chinese 
      Academy of Sciences, Xiamen 361021, PR China; Ning bo Urban Environment 
      Observation and Research Station, Chinese Academy of Sciences, Ningbo 315830, PR 
      China.
FAU - Gong, Dirong
AU  - Gong D
AD  - Department of Polymer Science and Engineering, Faculty of Materials Science and 
      Chemical Engineering, Ningbo University, Ningbo 315211, PR China.
FAU - Xu, Bin
AU  - Xu B
AD  - Key Lab of Urban Environment and Health, Institute of Urban Environment, Chinese 
      Academy of Sciences, Xiamen 361021, PR China.
FAU - Chi, Qiaoqiao
AU  - Chi Q
AD  - Key Lab of Urban Environment and Health, Institute of Urban Environment, Chinese 
      Academy of Sciences, Xiamen 361021, PR China.
FAU - Zhang, Xian
AU  - Zhang X
AD  - Key Lab of Urban Environment and Health, Institute of Urban Environment, Chinese 
      Academy of Sciences, Xiamen 361021, PR China. Electronic address: 
      xzhang@iue.ac.cn.
LA  - eng
PT  - Journal Article
DEP - 20150925
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
OTO - NOTNLM
OT  - Chromium
OT  - HPLC-ICP-MS
OT  - Solid phase extraction
OT  - Speciation
OT  - Wastewater
EDAT- 2015/11/26 06:00
MHDA- 2015/11/26 06:01
CRDT- 2015/11/24 06:00
PHST- 2015/06/29 00:00 [received]
PHST- 2015/09/16 00:00 [revised]
PHST- 2015/09/19 00:00 [accepted]
PHST- 2015/11/24 06:00 [entrez]
PHST- 2015/11/26 06:00 [pubmed]
PHST- 2015/11/26 06:01 [medline]
AID - S0039-9140(15)30338-6 [pii]
AID - 10.1016/j.talanta.2015.09.047 [doi]
PST - ppublish
SO  - Talanta. 2016 Jan 15;147:155-61. doi: 10.1016/j.talanta.2015.09.047. Epub 2015 
      Sep 25.