PMID- 26601711
OWN - NLM
STAT- MEDLINE
DCOM- 20160527
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1422
DP  - 2015 Nov 27
TI  - Simultaneous determination of trace benzotriazoles and benzothiazoles in water by 
      large-volume injection/gas chromatography-mass spectrometry.
PG  - 270-276
LID - S0021-9673(15)01461-2 [pii]
LID - 10.1016/j.chroma.2015.10.017 [doi]
AB  - Benzotriazole (BTR) and benzothiazole (BTH) derivatives have been acknowledged as 
      emerging pollutants due to their widespread contamination in the environment and 
      their adverse effects on aquatic organisms. A rapid and reliable analytical 
      method, based on solid phase extraction (SPE) and large-volume injection, 
      derivatized with N-tert-butyldimethylsilyl-N-methyltrifluoroacetamide (MTBSTFA), 
      and analyzed by gas chromatography-mass spectrometry (GC-MS), was developed for 
      the determination of six 1,2,3-benzotriazoles and six 1,3-benzothiazoles in 
      aquatic matrices. It was demonstrated that MTBSTFA had a better overall 
      performance compared with N-methyl-N-(trimethylsilyl)trifluoroacetamide (MSTFA) 
      and N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA). The method detection 
      limits in tap water, river water and effluent samples were 0.050-1.3 ng L(-1), 
      0.057-1.8 ng L(-1) and 0.10-4.0 ng L(-1), respectively. Mean recoveries of the 
      target analytes at different aquatic matrices, ranged from 43% to 131% with 
      relative standard deviations (RSDs) below 17%. The method was successfully 
      employed to river water and effluent sewage samples collected from a sewage 
      treatment plant in Germany. Seven target compounds were detected with the maximum 
      concentration up to 2.9 mug L(-1) for 4-Me-BTR in the effluent sample.
FAU - Xu, Weihai
AU  - Xu W
AD  - CAS Key Laboratory of Marginal Sea Geology, South China Sea Institute of 
      Oceanology, Chinese Academy of Sciences, Guangzhou 510301, China; Department 
      Applied Geology, Geoscience Centre of the University of Gottingen, Gottingen 
      37077, Germany. Electronic address: whxu@scsio.ac.cn.
FAU - Yan, Wen
AU  - Yan W
AD  - CAS Key Laboratory of Marginal Sea Geology, South China Sea Institute of 
      Oceanology, Chinese Academy of Sciences, Guangzhou 510301, China.
FAU - Licha, Tobias
AU  - Licha T
AD  - Department Applied Geology, Geoscience Centre of the University of Gottingen, 
      Gottingen 37077, Germany. Electronic address: tobias.licha@geo.uni-goettingen.de.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Benzothiazoles)
RN  - 0 (Sewage)
RN  - 0 (Triazoles)
RN  - 0 (Water Pollutants, Chemical)
RN  - 059QF0KO0R (Water)
RN  - 86110UXM5Y (benzotriazole)
RN  - G5BW2593EP (benzothiazole)
SB  - IM
MH  - Benzothiazoles/*analysis
MH  - Chemistry Techniques, Analytical/*methods
MH  - *Gas Chromatography-Mass Spectrometry
MH  - Germany
MH  - Limit of Detection
MH  - Sewage/chemistry
MH  - Solid Phase Extraction
MH  - Triazoles/*analysis
MH  - Water/*chemistry
MH  - Water Pollutants, Chemical/analysis
EDAT- 2015/11/26 06:00
MHDA- 2016/05/28 06:00
CRDT- 2015/11/26 06:00
PHST- 2015/07/15 00:00 [received]
PHST- 2015/10/08 00:00 [revised]
PHST- 2015/10/08 00:00 [accepted]
PHST- 2015/11/26 06:00 [entrez]
PHST- 2015/11/26 06:00 [pubmed]
PHST- 2016/05/28 06:00 [medline]
AID - S0021-9673(15)01461-2 [pii]
AID - 10.1016/j.chroma.2015.10.017 [doi]
PST - ppublish
SO  - J Chromatogr A. 2015 Nov 27;1422:270-276. doi: 10.1016/j.chroma.2015.10.017.