PMID- 26686107 OWN - NLM STAT- MEDLINE DCOM- 20161017 LR - 20170625 IS - 1879-1344 (Electronic) IS - 0144-8617 (Linking) VI - 137 DP - 2016 Feb 10 TI - Competitive fluorescence assay for specific recognition of atrazine by magnetic molecularly imprinted polymer based on Fe3O4-chitosan. PG - 75-81 LID - S0144-8617(15)01042-5 [pii] LID - 10.1016/j.carbpol.2015.10.062 [doi] AB - A novel fluorescence sensing strategy for determination of atrazine in tap water involving direct competition between atrazine and 5-(4,6-dichlorotriazinyl) aminofluorescein (5-DTAF), and which exploits magnetic molecularly imprinted polymer (MMIP), has been developed. The MMIP, based on Fe3O4-chitosan nanoparticles, was synthesized to recognize specific binding sites of atrazine. The recognition capability and selectivity of the MMIP for atrazine and other triazine herbicides was investigated. Under optimal conditions, the competitive reaction between 5-DTAF and atrazine was performed to permit quantitation. Fluorescence intensity changes at 515 nm was linearly related to the logarithm of the atrazine concentration for the range 2.32-185.4 muM. The detection limit for atrazine was 0.86muM (S/N=3) and recoveries were 77.6-115% in spiked tap water samples. CI - Copyright (c) 2015 Elsevier Ltd. All rights reserved. FAU - Liu, Guangyang AU - Liu G AD - School of Food Science and Engineering, Harbin Institute of Technology, Harbin 150090, PR China; Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. FAU - Li, Tengfei AU - Li T AD - Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. FAU - Yang, Xin AU - Yang X AD - School of Food Science and Engineering, Harbin Institute of Technology, Harbin 150090, PR China. Electronic address: yangxin@hit.edu.cn. FAU - She, Yongxin AU - She Y AD - Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. FAU - Wang, Miao AU - Wang M AD - Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. FAU - Wang, Jing AU - Wang J AD - School of Food Science and Engineering, Harbin Institute of Technology, Harbin 150090, PR China; Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. Electronic address: w_jing2001@126.com. FAU - Zhang, Min AU - Zhang M AD - School of Food Science and Engineering, Harbin Institute of Technology, Harbin 150090, PR China. FAU - Wang, Shanshan AU - Wang S AD - Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. FAU - Jin, Fen AU - Jin F AD - Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. FAU - Jin, Maojun AU - Jin M AD - Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. FAU - Shao, Hua AU - Shao H AD - Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. FAU - Jiang, Zejun AU - Jiang Z AD - Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. FAU - Yu, Hailong AU - Yu H AD - Key Laboratory of Agro-Product Quality and Safety, Institute of Quality Standard and Testing Technology for Agro-Product, Chinese Academy of Agricultural Sciences, Beijing 100081, PR China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20151017 PL - England TA - Carbohydr Polym JT - Carbohydrate polymers JID - 8307156 RN - 0 (Polymers) RN - 9012-76-4 (Chitosan) RN - QJA9M5H4IM (Atrazine) RN - XM0M87F357 (Ferrosoferric Oxide) SB - IM MH - Atrazine/*chemistry MH - Chitosan/*chemistry MH - Ferrosoferric Oxide/*chemistry MH - Fluorescence MH - Molecular Imprinting/*methods MH - Polymers/*chemistry OTO - NOTNLM OT - Atrazine OT - Fe(3)O(4)-chitosan nanoparticles OT - Fluorescence assay OT - Magnetic molecularly imprinted polymers EDAT- 2015/12/22 06:00 MHDA- 2016/10/19 06:00 CRDT- 2015/12/22 06:00 PHST- 2015/06/28 00:00 [received] PHST- 2015/10/13 00:00 [revised] PHST- 2015/10/15 00:00 [accepted] PHST- 2015/12/22 06:00 [entrez] PHST- 2015/12/22 06:00 [pubmed] PHST- 2016/10/19 06:00 [medline] AID - S0144-8617(15)01042-5 [pii] AID - 10.1016/j.carbpol.2015.10.062 [doi] PST - ppublish SO - Carbohydr Polym. 2016 Feb 10;137:75-81. doi: 10.1016/j.carbpol.2015.10.062. Epub 2015 Oct 17.