PMID- 26702592
OWN - NLM
STAT- MEDLINE
DCOM- 20160815
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1427
DP  - 2016 Jan 4
TI  - In situ rapid preparation of homochiral metal-organic framework coated column for 
      open tubular capillary electrochromatography.
PG  - 125-33
LID - S0021-9673(15)01789-6 [pii]
LID - 10.1016/j.chroma.2015.12.020 [doi]
AB  - Fabricating metal-organic frameworks (MOFs) with the use of nucleating agents in 
      the microenvironment have attracted increasing attention recently. Herein, a 
      simple and rapid synthesis method was developed to in situ fabricate homochiral 
      MOF [Zn(s-nip)2]n in the capillary inner wall by using ZnO nanoparticles as 
      efficient nucleating agents for open tubular capillary electrochromatography 
      (OT-CEC) separation of monoamine neurotransmitters enantiomers of epinephrine, 
      isoprenaline and synephrine, the diastereoisomers of ephedrine and 
      pseudoephedrine, the isomers of nitrophenols and analogues of bisphenols with 
      good resolution. The relative standard deviations (RSDs) for the analytes 
      migration time of intra-day, inter-day and column-to-column were in the range of 
      0.8-2.1% (n=10), 0.3-3.2% (n=3) and 3.2-9.3% (n=3), respectively. Additionally, 
      the homochiral MOF [Zn(s-nip)2]n coated capillary column could be successively 
      used over 260 runs without observable change in the separation efficiency.
CI  - Copyright (c) 2015 Elsevier B.V. All rights reserved.
FAU - Pan, Congjie
AU  - Pan C
AD  - State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 
      730000, China; Department of Chemistry, Lanzhou University, Lanzhou 730000, 
      China.
FAU - Wang, Weifeng
AU  - Wang W
AD  - State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 
      730000, China; Department of Chemistry, Lanzhou University, Lanzhou 730000, 
      China.
FAU - Chen, Xingguo
AU  - Chen X
AD  - State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 
      730000, China; Department of Chemistry, Lanzhou University, Lanzhou 730000, 
      China; Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of 
      Gansu Province, Lanzhou 730000, China. Electronic address: chenxg@lzu.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20151211
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 ((S)-2-(1,8-naphthalimido)-3-(4-imidazole)propanoate)
RN  - 0 (Biogenic Monoamines)
RN  - 0 (Coordination Complexes)
RN  - 0 (Imidazoles)
RN  - 0 (Neurotransmitter Agents)
RN  - 0 (Nitrophenols)
RN  - 0 (Propionates)
RN  - J41CSQ7QDS (Zinc)
RN  - SOI2LOH54Z (Zinc Oxide)
SB  - IM
MH  - Biogenic Monoamines/analysis
MH  - Capillary Electrochromatography/*instrumentation/methods
MH  - Coordination Complexes/chemical synthesis/*chemistry
MH  - Imidazoles/chemical synthesis/chemistry
MH  - Metal Nanoparticles
MH  - Neurotransmitter Agents/analysis
MH  - Nitrophenols/analysis
MH  - Propionates/chemical synthesis/chemistry
MH  - Stereoisomerism
MH  - *Zinc
MH  - Zinc Oxide/chemistry
OTO - NOTNLM
OT  - Homochiral metal-organic framework
OT  - In situ synthesis
OT  - Nucleating agent
OT  - Open tubular capillary electrochromatography
OT  - ZnO nanoparticles
EDAT- 2015/12/26 06:00
MHDA- 2016/08/16 06:00
CRDT- 2015/12/26 06:00
PHST- 2015/09/14 00:00 [received]
PHST- 2015/12/03 00:00 [revised]
PHST- 2015/12/08 00:00 [accepted]
PHST- 2015/12/26 06:00 [entrez]
PHST- 2015/12/26 06:00 [pubmed]
PHST- 2016/08/16 06:00 [medline]
AID - S0021-9673(15)01789-6 [pii]
AID - 10.1016/j.chroma.2015.12.020 [doi]
PST - ppublish
SO  - J Chromatogr A. 2016 Jan 4;1427:125-33. doi: 10.1016/j.chroma.2015.12.020. Epub 
      2015 Dec 11.