PMID- 26781716 OWN - NLM STAT- MEDLINE DCOM- 20160627 LR - 20220318 IS - 1573-2959 (Electronic) IS - 0167-6369 (Linking) VI - 188 IP - 2 DP - 2016 Feb TI - Occurrence and spatial distribution of pesticide residues in butter and ghee (clarified butter fat) in Punjab (India). PG - 100 LID - 10.1007/s10661-016-5115-8 [doi] AB - The present study was undertaken to monitor organochlorine, organophosphate, and synthetic pyrethroid pesticide residues in butter (n = 55) and ghee (n = 56) samples collected from three different regions of Punjab. The estimation of pesticide residues was done by multiple residue analytical technique using gas chromatography equipped with GC-ECD and GC-FTD. The confirmation of residues was done on gas chromatography mass spectrometry in both selective ion monitoring (SIM) and scan mode. Results indicated the presence of hexacholorocyclohexane (HCH) and p,p' DDE as predominant contaminant in both butter and ghee. Residues of HCH were detected in 25 and 23% samples of butter and ghee, respectively, while residues of p,p' DDE were recorded in 29 and 25% of butter and ghee samples, respectively. None of the butter and ghee sample violated the MRL values of 200 ng g(-1) for HCH and 1250 ng g(-1) for dichorodiphenyl tricholorethane (DDT). The presence of endosulfan, cypermethrin, fenvalerate, deltamethrin, and chlorpyrifos were observed in a few butter and ghee samples at traces. The spatial variation for comparative occurrence of pesticide residues indicated higher levels in the south-western region of Punjab. Additionally, the temporal variation indicated the significant reduction of HCH and DDT levels in butter and ghee in Punjab. FAU - Bedi, J S AU - Bedi JS AD - School of Public Health and Zoonoses, Guru Angad Dev Veterinary and Animal Sciences University, Ludhiana, 141004, Punjab, India. bedijasbir78@gmail.com. FAU - Gill, J P S AU - Gill JP AD - School of Public Health and Zoonoses, Guru Angad Dev Veterinary and Animal Sciences University, Ludhiana, 141004, Punjab, India. FAU - Aulakh, R S AU - Aulakh RS AD - School of Public Health and Zoonoses, Guru Angad Dev Veterinary and Animal Sciences University, Ludhiana, 141004, Punjab, India. FAU - Kaur, Prabhjit AU - Kaur P AD - School of Public Health and Zoonoses, Guru Angad Dev Veterinary and Animal Sciences University, Ludhiana, 141004, Punjab, India. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20160118 PL - Netherlands TA - Environ Monit Assess JT - Environmental monitoring and assessment JID - 8508350 RN - 0 (Ghee) RN - 0 (Nitriles) RN - 0 (Pesticide Residues) RN - 0 (Pyrethrins) RN - 1TR49121NP (cypermethrin) RN - 2JTS8R821G (decamethrin) RN - 8029-34-3 (Butter) RN - JCS58I644W (Chlorpyrifos) RN - OKA6A6ZD4K (Endosulfan) RN - Z6MXZ39302 (fenvalerate) SB - IM MH - Butter/*analysis MH - Chlorpyrifos/analysis MH - Chromatography, Gas MH - Endosulfan/analysis MH - Environmental Monitoring MH - Food Contamination/*analysis MH - Gas Chromatography-Mass Spectrometry MH - Ghee/*analysis MH - India MH - Nitriles MH - Pesticide Residues/*analysis MH - Pyrethrins OTO - NOTNLM OT - Butter OT - Ghee OT - India OT - Pesticides residues OT - Punjab EDAT- 2016/01/20 06:00 MHDA- 2016/06/28 06:00 CRDT- 2016/01/20 06:00 PHST- 2015/10/05 00:00 [received] PHST- 2016/01/12 00:00 [accepted] PHST- 2016/01/20 06:00 [entrez] PHST- 2016/01/20 06:00 [pubmed] PHST- 2016/06/28 06:00 [medline] AID - 10.1007/s10661-016-5115-8 [pii] AID - 10.1007/s10661-016-5115-8 [doi] PST - ppublish SO - Environ Monit Assess. 2016 Feb;188(2):100. doi: 10.1007/s10661-016-5115-8. Epub 2016 Jan 18.