PMID- 26785217
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20160628
LR  - 20160229
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 307
DP  - 2016 Apr 15
TI  - Validating carbonation parameters of alkaline solid wastes via integrated thermal 
      analyses: Principles and applications.
PG  - 253-62
LID - S0304-3894(15)30325-3 [pii]
LID - 10.1016/j.jhazmat.2015.12.065 [doi]
AB  - Accelerated carbonation of alkaline solid wastes is an attractive method for CO2 
      capture and utilization. However, the evaluation criteria of CaCO3 content in 
      solid wastes and the way to interpret thermal analysis profiles were found to be 
      quite different among the literature. In this investigation, an integrated 
      thermal analyses for determining carbonation parameters in basic oxygen furnace 
      slag (BOFS) were proposed based on thermogravimetric (TG), derivative 
      thermogravimetric (DTG), and differential scanning calorimetry (DSC) analyses. A 
      modified method of TG-DTG interpretation was proposed by considering the 
      consecutive weight loss of sample with 200-900 degrees C because the decomposition of 
      various hydrated compounds caused variances in estimates by using conventional 
      methods of TG interpretation. Different quantities of reference CaCO3 standards, 
      carbonated BOFS samples and synthetic CaCO3/BOFS mixtures were prepared for 
      evaluating the data quality of the modified TG-DTG interpretation, in terms of 
      precision and accuracy. The quantitative results of the modified TG-DTG method 
      were also validated by DSC analysis. In addition, to confirm the TG-DTG results, 
      the evolved gas analysis was performed by mass spectrometer and Fourier transform 
      infrared spectroscopy for detection of the gaseous compounds released during 
      heating. Furthermore, the decomposition kinetics and thermodynamics of CaCO3 in 
      BOFS was evaluated using Arrhenius equation and Kissinger equation. The proposed 
      integrated thermal analyses for determining CaCO3 content in alkaline wastes was 
      precise and accurate, thereby enabling to effectively assess the CO2 capture 
      capacity of alkaline wastes for mineral carbonation.
CI  - Copyright (c) 2015 Elsevier B.V. All rights reserved.
FAU - Pan, Shu-Yuan
AU  - Pan SY
AD  - Graduate Institute of Environmental Engineering, National Taiwan University, 
      Taipei 10673, Taiwan.
FAU - Chang, E-E
AU  - Chang EE
AD  - Department of Biochemistry, Taipei Medical University, Taipei 110, Taiwan.
FAU - Kim, Hyunook
AU  - Kim H
AD  - Department of Environmental Engineering, University of Seoul, Seoul 130-743, 
      South Korea.
FAU - Chen, Yi-Hung
AU  - Chen YH
AD  - Department of Chemical Engineering and Biotechnology, National Taipei University 
      of Technology, Taipei 10608, Taiwan.
FAU - Chiang, Pen-Chi
AU  - Chiang PC
AD  - Graduate Institute of Environmental Engineering, National Taiwan University, 
      Taipei 10673, Taiwan. Electronic address: pcchiang@ntu.edu.tw.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20160104
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
OTO - NOTNLM
OT  - Analytical
OT  - CO(2) fixation
OT  - Kissinger equation
OT  - Mineralization
OT  - Stabilization
EDAT- 2016/01/20 06:00
MHDA- 2016/01/20 06:01
CRDT- 2016/01/20 06:00
PHST- 2015/10/22 00:00 [received]
PHST- 2015/12/29 00:00 [revised]
PHST- 2015/12/30 00:00 [accepted]
PHST- 2016/01/20 06:00 [entrez]
PHST- 2016/01/20 06:00 [pubmed]
PHST- 2016/01/20 06:01 [medline]
AID - S0304-3894(15)30325-3 [pii]
AID - 10.1016/j.jhazmat.2015.12.065 [doi]
PST - ppublish
SO  - J Hazard Mater. 2016 Apr 15;307:253-62. doi: 10.1016/j.jhazmat.2015.12.065. Epub 
      2016 Jan 4.