PMID- 26838413
OWN - NLM
STAT- MEDLINE
DCOM- 20161101
LR  - 20161230
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 150
DP  - 2016 Apr 1
TI  - Polyaniline/cyclodextrin composite coated stir bar sorptive extraction combined 
      with high performance liquid chromatography-ultraviolet detection for the 
      analysis of trace polychlorinated biphenyls in environmental waters.
PG  - 310-8
LID - S0039-9140(15)30553-1 [pii]
LID - 10.1016/j.talanta.2015.12.025 [doi]
AB  - A novel polyaniline/alpha-cyclodextrin (PANI/alpha-CD) composite coated stir bar was 
      prepared by sol-gel process for the analysis of polychlorinated biphenyls (PCBs) 
      in this work. The preparation reproducibility of the PANI/alpha-CD-coated stir bar 
      was good, with relative standard deviations (RSDs) ranging from 2.3% to 3.7% 
      (n=7) and 2.0% to 3.8% (n=7) for bar to bar and batch to batch, respectively. 
      Based on it, a novel method of PANI/alpha-CD-coated stir bar sorptive extraction 
      (SBSE) followed by high performance liquid chromatography-ultraviolet (HPLC-UV) 
      detection was developed for the determination of trace PCBs in environmental 
      waters. To obtain the best extraction performance for target PCBs, several 
      parameters affecting SBSE, such as extraction time, stirring rate, and ionic 
      strength were investigated. Under optimal experimental conditions, the limits of 
      detection (LODs) of the proposed method for seven PCBs were in the range of 
      0.048-0.22 mug/L, and the RSDs were 5.3-9.8% (n=7, c=1 mug/L). Enrichment factors 
      (EFs) ranging from 39.8 to 68.4-fold (theoretical EF, 83.3-fold) for target 
      analytes were achieved. The proposed method was successfully applied for the 
      determination of seven target PCBs in Yangtze River water and East Lake water, 
      and the recoveries were in the range of 73.0-120% for the spiked East Lake water 
      samples and 82.7-121% for the spiked Yangtze River water samples, respectively.
CI  - Copyright (c) 2015 Elsevier B.V. All rights reserved.
FAU - Lei, Yun
AU  - Lei Y
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of 
      Education), Department of Chemistry, Wuhan University, Wuhan 430072, PR China.
FAU - He, Man
AU  - He M
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of 
      Education), Department of Chemistry, Wuhan University, Wuhan 430072, PR China.
FAU - Chen, Beibei
AU  - Chen B
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of 
      Education), Department of Chemistry, Wuhan University, Wuhan 430072, PR China.
FAU - Hu, Bin
AU  - Hu B
AD  - Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of 
      Education), Department of Chemistry, Wuhan University, Wuhan 430072, PR China. 
      Electronic address: binhu@whu.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20151219
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Aniline Compounds)
RN  - 0 (Salts)
RN  - 0 (Solvents)
RN  - 0 (Water Pollutants, Chemical)
RN  - 0 (alpha-Cyclodextrins)
RN  - 0 (polyaniline)
RN  - 059QF0KO0R (Water)
RN  - DFC2HB4I0K (Polychlorinated Biphenyls)
RN  - Z1LH97KTRM (alpha-cyclodextrin)
SB  - IM
MH  - Aniline Compounds/*chemistry
MH  - Chemical Fractionation/*methods
MH  - Chromatography, High Pressure Liquid
MH  - *Limit of Detection
MH  - Polychlorinated Biphenyls/*analysis/chemistry/*isolation & purification
MH  - Reproducibility of Results
MH  - Rivers/chemistry
MH  - Salts/chemistry
MH  - Solvents/chemistry
MH  - Spectrophotometry, Ultraviolet
MH  - Time Factors
MH  - Water/*chemistry
MH  - Water Pollutants, Chemical/analysis/chemistry/isolation & purification
MH  - alpha-Cyclodextrins/*chemistry
OTO - NOTNLM
OT  - Environmental waters
OT  - High performance liquid chromatography
OT  - Polyaniline/cyclodextrin composite coating
OT  - Polychlorinated biphenyls
OT  - Stir bar sorptive extraction
EDAT- 2016/02/04 06:00
MHDA- 2016/11/02 06:00
CRDT- 2016/02/04 06:00
PHST- 2015/10/22 00:00 [received]
PHST- 2015/11/30 00:00 [revised]
PHST- 2015/12/10 00:00 [accepted]
PHST- 2016/02/04 06:00 [entrez]
PHST- 2016/02/04 06:00 [pubmed]
PHST- 2016/11/02 06:00 [medline]
AID - S0039-9140(15)30553-1 [pii]
AID - 10.1016/j.talanta.2015.12.025 [doi]
PST - ppublish
SO  - Talanta. 2016 Apr 1;150:310-8. doi: 10.1016/j.talanta.2015.12.025. Epub 2015 Dec 
      19.