PMID- 26843028 OWN - NLM STAT- MEDLINE DCOM- 20170111 LR - 20181202 IS - 1873-6424 (Electronic) IS - 0269-7491 (Linking) VI - 217 DP - 2016 Oct TI - The TOMPs ambient air monitoring network - Continuous data on UK air quality for over 20 years. PG - 42-51 LID - S0269-7491(16)30033-1 [pii] LID - 10.1016/j.envpol.2016.01.033 [doi] AB - Long-term air monitoring datasets are needed for persistent organic pollutants (POPs) to assess the effectiveness of source abatement measures and the factors controlling ambient levels. The Toxic Organic Micro Pollutants (TOMPs) Network, which has operated since 1991, collects ambient air samples at six sites across England and Scotland, using high-volume active air samplers. The network provides long-term ambient air trend data for a range of POPs at both urban and rural locations. Data from the network provides the UK Government, regulators and researchers with valuable information on emission/source controls and on the effectiveness of international chemicals regulation such as the Stockholm Convention and UN/ECE Protocol on POPs. The target chemicals of TOMPs have been polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and, since 2010, polybrominated diphenyl ethers (PBDEs). The continuous monitoring of these compounds demonstrates the constant decline in UK air concentrations over the last two decades, with average clearance rates for PCDD/Fs in urban locations of 5.1 years and for PCBs across all sites 6.6 years. No significant declines in rural locations for PCDD/Fs have been observed. There is a strong observable link between the declining ambient air concentrations and the emission reductions estimated in the annually produced National Atmospheric Emission Inventory (NAEI) dataset. These findings clearly demonstrate the unique strengths of long-term consistent datasets for the evaluation of the success of chemical regulation and control. CI - Copyright (c) 2016 Elsevier Ltd. All rights reserved. FAU - Graf, Carola AU - Graf C AD - Lancaster Environment Centre, Lancaster University, UK. FAU - Katsoyiannis, Athanasios AU - Katsoyiannis A AD - Lancaster Environment Centre, Lancaster University, UK. FAU - Jones, Kevin C AU - Jones KC AD - Lancaster Environment Centre, Lancaster University, UK. FAU - Sweetman, Andrew J AU - Sweetman AJ AD - Lancaster Environment Centre, Lancaster University, UK. Electronic address: a.sweetman@lancaster.ac.uk. LA - eng PT - Journal Article DEP - 20160201 PL - England TA - Environ Pollut JT - Environmental pollution (Barking, Essex : 1987) JID - 8804476 RN - 0 (Air Pollutants) RN - 0 (Dibenzofurans, Polychlorinated) RN - 0 (Halogenated Diphenyl Ethers) RN - 0 (Polychlorinated Dibenzodioxins) RN - 0 (Polycyclic Aromatic Hydrocarbons) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Air Pollutants/*analysis MH - Atmosphere/*chemistry MH - Dibenzofurans, Polychlorinated/analysis MH - England MH - *Environmental Monitoring MH - Halogenated Diphenyl Ethers/analysis MH - Polychlorinated Biphenyls/analysis MH - Polychlorinated Dibenzodioxins/analysis MH - Polycyclic Aromatic Hydrocarbons/analysis MH - Scotland MH - Time Factors OTO - NOTNLM OT - Air monitoring OT - Long-term OT - POPs OT - Stockholm Convention OT - Time trends EDAT- 2016/02/05 06:00 MHDA- 2017/01/12 06:00 CRDT- 2016/02/05 06:00 PHST- 2015/09/10 00:00 [received] PHST- 2016/01/11 00:00 [revised] PHST- 2016/01/13 00:00 [accepted] PHST- 2016/02/05 06:00 [entrez] PHST- 2016/02/05 06:00 [pubmed] PHST- 2017/01/12 06:00 [medline] AID - S0269-7491(16)30033-1 [pii] AID - 10.1016/j.envpol.2016.01.033 [doi] PST - ppublish SO - Environ Pollut. 2016 Oct;217:42-51. doi: 10.1016/j.envpol.2016.01.033. Epub 2016 Feb 1.