PMID- 26852352
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20160614
LR  - 20170725
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 468
DP  - 2016 Apr 15
TI  - Synthesis, characterization, and visible-light-driven photocatalytic performance 
      of W-SBA15.
PG  - 284-291
LID - S0021-9797(16)30078-9 [pii]
LID - 10.1016/j.jcis.2016.01.077 [doi]
AB  - A series of tungsten-containing mesoporous SBA15 with different tungsten contents 
      were prepared through a direct co-condensation sol-gel method and then analyzed 
      by various techniques. XRD patterns revealed that the original mesoporous 
      morphology was maintained after introducing tungsten species and forms of 
      tungsten species were changed from incorporated tungsten to isolated tungsten 
      species or low oligomeric tungsten oxide species, and finally to crystalline WO3 
      with the increase of tungsten precursor content, which were also proven by HRTEM 
      images, UV-Vis DRS, and FT-IR spectra. The W-SBA15 samples exhibited satisfactory 
      photocatalytic performance toward degradation of dye Rhodamine B (RhB) and 
      2,4-dichlorophenol (2,4-DCP). In particular, the best candidate, sample 
      10%W-SBA15 showed an apparent reaction rate constant for RhB that was nearly 10 
      times as high as that of bulk WO3. The enhancement of photocatalytic capability 
      was attributed to the mesoporous morphology with enlarged surface areas, 
      negatively charged surface, and favorable tungsten forms such as incorporated 
      tungsten, isolated tungsten or low oligomeric tungsten oxide species. In 
      addition, active radicals trapping experiments and DMPO spin-trapping ESR spectra 
      indicated that photogenerated holes were major oxidative species during 
      photocatalysis.
CI  - Copyright (c) 2016 Elsevier Inc. All rights reserved.
FAU - Chang, Fei
AU  - Chang F
AD  - School of Environment and Architecture, University of Shanghai for Science and 
      Technology, Shanghai 200093, PR China. Electronic address: feichang@usst.edu.cn.
FAU - Wang, Jie
AU  - Wang J
AD  - School of Environment and Architecture, University of Shanghai for Science and 
      Technology, Shanghai 200093, PR China.
FAU - Luo, Jieru
AU  - Luo J
AD  - School of Environment and Architecture, University of Shanghai for Science and 
      Technology, Shanghai 200093, PR China.
FAU - Sun, Junrong
AU  - Sun J
AD  - School of Environment and Architecture, University of Shanghai for Science and 
      Technology, Shanghai 200093, PR China.
FAU - Hu, Xuefeng
AU  - Hu X
AD  - Key Laboratory of Coastal Zone Environmental Processes and Ecological 
      Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of 
      Sciences, Yantai, Shandong 264003, PR China. Electronic address: xfhu@yic.ac.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20160204
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
OTO - NOTNLM
OT  - 2,4-Dichlorophenol
OT  - Mechanism
OT  - Photocatalysis
OT  - Rhodamine B
OT  - W-SBA15
EDAT- 2016/02/08 06:00
MHDA- 2016/02/08 06:01
CRDT- 2016/02/08 06:00
PHST- 2015/09/29 00:00 [received]
PHST- 2016/01/29 00:00 [revised]
PHST- 2016/01/30 00:00 [accepted]
PHST- 2016/02/08 06:00 [entrez]
PHST- 2016/02/08 06:00 [pubmed]
PHST- 2016/02/08 06:01 [medline]
AID - S0021-9797(16)30078-9 [pii]
AID - 10.1016/j.jcis.2016.01.077 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2016 Apr 15;468:284-291. doi: 
      10.1016/j.jcis.2016.01.077. Epub 2016 Feb 4.