PMID- 26864607
OWN - NLM
STAT- MEDLINE
DCOM- 20161213
LR  - 20161230
IS  - 1522-2683 (Electronic)
IS  - 0173-0835 (Linking)
VI  - 37
IP  - 7-8
DP  - 2016 Apr
TI  - Stability of nicotinate and dodecyl sulfate in a Lewis acidic ionic liquid for 
      aluminum electroplating and characterization of their degradation products.
PG  - 1095-100
LID - 10.1002/elps.201500452 [doi]
AB  - Plating bath additives are essential for optimization of the morphology of 
      electroplated layers. The ionic liquid 1-ethyl-3-methylimidazolium (EMIM) 
      chloride plus 1.5 mol equivalents of AlCl3 has great potential for electroplating 
      of aluminum. In this study, the chemical and electrochemical stability of the 
      additives EMIM-nicotinate and sodium dodecyl sulfate and their effect on the 
      stability of EMIM was investigated and analyzed. Nicotinate and its 
      electrochemical decomposition product beta-picoline could be detected and we show 
      with a single HPLC-UV-MS method that EMIM is not affected by the decomposition of 
      this additive. An adapted standard HPLC-UV-MS method together with GC-MS and ion 
      chromatography was used to analyze the decomposition products of SDS and possible 
      realkylation products of EMIM. Several volatile medium and short chain-length 
      alkanes as well as sulfate ions have been found as decomposition products of SDS. 
      Alkenium ions formed as intermediates during the decomposition of SDS realkylate 
      EMIM to produce mono- up to pentasubstituted alkyl-imidazoles. A reaction pathway 
      involving Wagner-Meerwein rearrangements and Friedel-Crafts alkylations has been 
      suggested to account for the formation of the detected products.
CI  - (c) 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Kosmus, Patrick
AU  - Kosmus P
AD  - Institute for Chemistry and Technology of Materials, Graz University of 
      Technology, NAWI Graz, Graz, Austria.
FAU - Steiner, Oliver
AU  - Steiner O
AD  - Institute for Chemistry, Analytical Chemistry, University of Graz, NAWI Graz, 
      Graz, Austria.
FAU - Goessler, Walter
AU  - Goessler W
AD  - Institute for Chemistry, Analytical Chemistry, University of Graz, NAWI Graz, 
      Graz, Austria.
FAU - Gollas, Bernhard
AU  - Gollas B
AD  - Institute for Chemistry and Technology of Materials, Graz University of 
      Technology, NAWI Graz, Graz, Austria.
FAU - Fauler, Gisela
AU  - Fauler G
AD  - VARTA Micro Innovation GmbH, Graz, Austria.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - Germany
TA  - Electrophoresis
JT  - Electrophoresis
JID - 8204476
RN  - 0 (Ionic Liquids)
RN  - 2679MF687A (Niacin)
RN  - 368GB5141J (Sodium Dodecyl Sulfate)
RN  - CPD4NFA903 (Aluminum)
RN  - DIQ16UC154 (dodecyl sulfate)
SB  - IM
MH  - Aluminum/*chemistry
MH  - Chromatography, High Pressure Liquid
MH  - Electroplating/*methods
MH  - Gas Chromatography-Mass Spectrometry
MH  - Ionic Liquids/*chemistry
MH  - Niacin/*chemistry
MH  - Sodium Dodecyl Sulfate/*chemistry
OTO - NOTNLM
OT  - Additive
OT  - Aluminum electroplating
OT  - GC MS
OT  - HPLC MS
OT  - Ionic liquids
EDAT- 2016/02/13 06:00
MHDA- 2016/12/15 06:00
CRDT- 2016/02/12 06:00
PHST- 2015/10/08 00:00 [received]
PHST- 2015/12/29 00:00 [revised]
PHST- 2016/01/29 00:00 [accepted]
PHST- 2016/02/12 06:00 [entrez]
PHST- 2016/02/13 06:00 [pubmed]
PHST- 2016/12/15 06:00 [medline]
AID - 10.1002/elps.201500452 [doi]
PST - ppublish
SO  - Electrophoresis. 2016 Apr;37(7-8):1095-100. doi: 10.1002/elps.201500452.