PMID- 26878901 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20160826 LR - 20160225 IS - 2040-3372 (Electronic) IS - 2040-3364 (Linking) VI - 8 IP - 9 DP - 2016 Mar 7 TI - In situ plasmonic Ag nanoparticle anchored TiO2 nanotube arrays as visible-light-driven photocatalysts for enhanced water splitting. PG - 5226-34 LID - 10.1039/c5nr08341a [doi] AB - An ultrasonication-assisted in situ deposition strategy was utilised to uniformly decorate plasmonic Ag nanoparticles on vertically aligned TiO2 nanotube arrays (NTAs) to construct a Ag@TiO2 NTA composite. The Ag nanoparticles act as efficient surface plasmon resonance (SPR) photosensitizers to drive photocatalytic water splitting under visible light irradiation. The Ag nanoparticles were uniformly deposited on the surface and inside the highly oriented TiO2 nanotubes. The visible-light-driven hydrogen production activities of silver nanoparticle anchored TiO2 nanotube array photocatalysts were evaluated using methanol as a sacrificial reagent in water under a 500 W Xe lamp with a UV light cutoff filter (lambda >/= 420 nm). It was found that the hydrogen production rate of the Ag@TiO2 NTAs prepared with ultrasonication-assisted deposition for 5 min was approximately 15 times higher than that of its pristine TiO2 NTAs counterpart. The highly efficient photocatalytic hydrogen evolution is attributed to the SPR effect of Ag for enhanced visible light absorption and boosting the photogenerated electron-hole separation/transfer. This strategy is promising for the design and construction of high efficiency TiO2 based photocatalysts for solar energy conversion. FAU - Ge, Ming-Zheng AU - Ge MZ AD - National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China. jyhuang81@suda.edu.cn kqzhang@suda.edu.cn yklai@suda.edu.cn. FAU - Cao, Chun-Yan AU - Cao CY AD - National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China. jyhuang81@suda.edu.cn kqzhang@suda.edu.cn yklai@suda.edu.cn. FAU - Li, Shu-Hui AU - Li SH AD - National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China. jyhuang81@suda.edu.cn kqzhang@suda.edu.cn yklai@suda.edu.cn. FAU - Tang, Yu-Xin AU - Tang YX AD - School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore. FAU - Wang, Lu-Ning AU - Wang LN AD - School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China. FAU - Qi, Ning AU - Qi N AD - National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China. jyhuang81@suda.edu.cn kqzhang@suda.edu.cn yklai@suda.edu.cn. FAU - Huang, Jian-Ying AU - Huang JY AD - National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China. jyhuang81@suda.edu.cn kqzhang@suda.edu.cn yklai@suda.edu.cn. FAU - Zhang, Ke-Qin AU - Zhang KQ AD - National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China. jyhuang81@suda.edu.cn kqzhang@suda.edu.cn yklai@suda.edu.cn and Research Center of Cooperative Innovation for Functional Organic/Polymer Material Micro/Nanofabrication, Soochow University, Suzhou, Jiangsu 215123, China. FAU - Al-Deyab, S S AU - Al-Deyab SS AD - Petrochemical Research Chair, Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia. FAU - Lai, Yue-Kun AU - Lai YK AD - National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China. jyhuang81@suda.edu.cn kqzhang@suda.edu.cn yklai@suda.edu.cn and Research Center of Cooperative Innovation for Functional Organic/Polymer Material Micro/Nanofabrication, Soochow University, Suzhou, Jiangsu 215123, China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - England TA - Nanoscale JT - Nanoscale JID - 101525249 EDAT- 2016/02/18 06:00 MHDA- 2016/02/18 06:01 CRDT- 2016/02/17 06:00 PHST- 2016/02/17 06:00 [entrez] PHST- 2016/02/18 06:00 [pubmed] PHST- 2016/02/18 06:01 [medline] AID - 10.1039/c5nr08341a [doi] PST - ppublish SO - Nanoscale. 2016 Mar 7;8(9):5226-34. doi: 10.1039/c5nr08341a.