PMID- 26897564
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20160711
LR  - 20170725
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 469
DP  - 2016 May 1
TI  - Oxidation of 2,4-dichlorophenol by non-radical mechanism using persulfate 
      activated by Fe/S modified carbon nanotubes.
PG  - 277-286
LID - S0021-9797(16)30067-4 [pii]
LID - 10.1016/j.jcis.2016.01.067 [doi]
AB  - The aim of this study was to develop a new approach for the activation of 
      persulfate (PS) based on carbon nanotubes (CNTs). Fe/S modified carbon nanotubes 
      (Fe/S-CNTs) were synthesized via impregnation-precipitation in the aqueous-phase 
      synthesis method. The morphologies and chemical states of the catalysts were 
      characterized and 2,4-dichlorophenol (2,4-DCP) was selected to investigate the 
      degradation performance using Fe/S-CNTs with PS. The results reveal that the 
      Fe/S-CNTs catalysts can significantly accelerate the removal of 2,4-DCP compared 
      to single PS or PS/CNTs. The catalytic capacity is also enhanced by S 
      modification and is affected by the solution pH. The iron loading content, PS 
      concentration and catalyst dosage could play important roles in the degradation. 
      A non-radical process of 2,4-DCP degradation is demonstrated for the first time 
      in the results of the radical scavengers and chloride ionic, as well as 
      persulfate decomposition. It is suggested that PS is first bonded with the 
      sp(2)-hybridized system and activated by iron oxide particles and iron-sulfur 
      complexes, then it reacts rapidly with the adsorbed 2,4-DCP.
CI  - Copyright (c) 2016 Elsevier Inc. All rights reserved.
FAU - Cheng, Xin
AU  - Cheng X
AD  - College of Architecture and Environment, Sichuan University, Chengdu 610065, 
      China.
FAU - Guo, Hongguang
AU  - Guo H
AD  - College of Architecture and Environment, Sichuan University, Chengdu 610065, 
      China; National Engineering Laboratory for Clean Technology of Leather 
      Manufacture, Sichuan University, Chengdu 610065, China. Electronic address: 
      hgguo@scu.edu.cn.
FAU - Zhang, Yongli
AU  - Zhang Y
AD  - College of Architecture and Environment, Sichuan University, Chengdu 610065, 
      China.
FAU - Liu, Yang
AU  - Liu Y
AD  - College of Architecture and Environment, Sichuan University, Chengdu 610065, 
      China.
FAU - Liu, Hongwei
AU  - Liu H
AD  - College of Architecture and Environment, Sichuan University, Chengdu 610065, 
      China.
FAU - Yang, Ying
AU  - Yang Y
AD  - College of Architecture and Environment, Sichuan University, Chengdu 610065, 
      China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20160128
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
OTO - NOTNLM
OT  - 2,4-Dichlorophenol
OT  - Carbon nanotubes
OT  - Fe/S modification
OT  - Non-radical
OT  - Persulfate oxidation
EDAT- 2016/02/22 06:00
MHDA- 2016/02/22 06:01
CRDT- 2016/02/22 06:00
PHST- 2015/11/23 00:00 [received]
PHST- 2016/01/25 00:00 [revised]
PHST- 2016/01/28 00:00 [accepted]
PHST- 2016/02/22 06:00 [entrez]
PHST- 2016/02/22 06:00 [pubmed]
PHST- 2016/02/22 06:01 [medline]
AID - S0021-9797(16)30067-4 [pii]
AID - 10.1016/j.jcis.2016.01.067 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2016 May 1;469:277-286. doi: 10.1016/j.jcis.2016.01.067. 
      Epub 2016 Jan 28.