PMID- 26909368 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20160224 LR - 20200930 IS - 2352-3409 (Print) IS - 2352-3409 (Electronic) IS - 2352-3409 (Linking) VI - 6 DP - 2016 Mar TI - Structural, thermal and photo-physical data of azo-aromatic TEMPO derivatives before and after their grafting to polyolefins. PG - 562-70 LID - 10.1016/j.dib.2015.12.047 [doi] AB - The data reported in this paper are complementary to the characterization of 4-(phenylazo)-benzoyl-2,2,6,6-tetramethylpiperidine-1-oxyl radical (AzO-TEMPO) and of the 4-(2-thienylazo)-benzoyl-2,2,6,6-tetramethylpiperidine-1-oxyl radical (ThiO-TEMPO) before and after their grafting to two polyethylene matrices (a copolymer ethylene/alpha-olefin (co-EO) and a high density polyethylene (HDPE)). Particularly the data reported in this paper confirm the structure (FT-IR analysis), the thermal (TGA and EPR) and the photo-physical (UV-vis) properties of the RO-TEMPO derivatives before and after their grafting. Herein, the FT-IR spectrum and TGA thermogram of ThiO-TEMPO were compared with those of AzO-TEMPO. Moreover, the superimposition of UV-vis spectra collected during the irradiation under 366 or 254 nm emitting lamp of AzO-TEMPO and ThiO-TEMPO in acetonitrile solution are reported. Finally, a complete DSC characterization of the functionalized POs is shown. DOI of original article: [1]. FAU - Cicogna, Francesca AU - Cicogna F AD - Istituto di Chimica dei Composti OrganoMetallici (ICCOM), Consiglio Nazionale delle Ricerche, SS Pisa, Via G. Moruzzi 1, 56124 Pisa, Italy. FAU - Domenichelli, Ilaria AU - Domenichelli I AD - Istituto di Chimica dei Composti OrganoMetallici (ICCOM), Consiglio Nazionale delle Ricerche, SS Pisa, Via G. Moruzzi 1, 56124 Pisa, Italy; Scuola Normale Superiore, Piazza dei Cavalieri 7, 56126 Pisa, Italy. FAU - Coiai, Serena AU - Coiai S AD - Istituto di Chimica dei Composti OrganoMetallici (ICCOM), Consiglio Nazionale delle Ricerche, SS Pisa, Via G. Moruzzi 1, 56124 Pisa, Italy. FAU - Bellina, Fabio AU - Bellina F AD - Istituto di Chimica dei Composti OrganoMetallici (ICCOM), Consiglio Nazionale delle Ricerche, SS Pisa, Via G. Moruzzi 1, 56124 Pisa, Italy; Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Pisa, Via G. Moruzzi 13, 56124 Pisa, Italy. FAU - Lessi, Marco AU - Lessi M AD - Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Pisa, Via G. Moruzzi 13, 56124 Pisa, Italy. FAU - Spiniello, Roberto AU - Spiniello R AD - Istituto di Chimica dei Composti OrganoMetallici (ICCOM), Consiglio Nazionale delle Ricerche, SS Pisa, Via G. Moruzzi 1, 56124 Pisa, Italy. FAU - Passaglia, Elisa AU - Passaglia E AD - Istituto di Chimica dei Composti OrganoMetallici (ICCOM), Consiglio Nazionale delle Ricerche, SS Pisa, Via G. Moruzzi 1, 56124 Pisa, Italy. LA - eng PT - Journal Article DEP - 20160106 PL - Netherlands TA - Data Brief JT - Data in brief JID - 101654995 PMC - PMC4731423 EDAT- 2016/02/26 06:00 MHDA- 2016/02/26 06:01 PMCR- 2016/01/06 CRDT- 2016/02/25 06:00 PHST- 2015/11/13 00:00 [received] PHST- 2015/12/11 00:00 [revised] PHST- 2015/12/22 00:00 [accepted] PHST- 2016/02/25 06:00 [entrez] PHST- 2016/02/26 06:00 [pubmed] PHST- 2016/02/26 06:01 [medline] PHST- 2016/01/06 00:00 [pmc-release] AID - S2352-3409(15)00413-8 [pii] AID - 10.1016/j.dib.2015.12.047 [doi] PST - epublish SO - Data Brief. 2016 Jan 6;6:562-70. doi: 10.1016/j.dib.2015.12.047. eCollection 2016 Mar.