PMID- 26950803 OWN - NLM STAT- MEDLINE DCOM- 20171108 LR - 20171108 IS - 1545-9632 (Electronic) IS - 1545-9624 (Linking) VI - 13 IP - 7 DP - 2016 Jul TI - Characterization of particle exposure in ferrochromium and stainless steel production. PG - 558-68 LID - 10.1080/15459624.2016.1159687 [doi] AB - This study describes workers' exposure to fine and ultrafine particles in the production chain of ferrochromium and stainless steel during sintering, ferrochromium smelting, stainless steel melting, and hot and cold rolling operations. Workers' personal exposure to inhalable dust was assessed using IOM sampler with a cellulose acetate filter (AAWP, diameter 25 mm; Millipore, Bedford, MA). Filter sampling methods were used to measure particle mass concentrations in fixed locations. Particle number concentrations and size distributions were examined using an SMPS+C sequential mobile particle sizer and counter (series 5.400, Grimm Aerosol Technik, Ainring, Germany), and a hand-held condensation particle counter (CPC, model 3007, TSI Incorporated, MN). The structure and elemental composition of particles were analyzed using TEM-EDXA (TEM: JEM-1220, JEOL, Tokyo, Japan; EDXA: Noran System Six, Thermo Fisher Scientific Inc., Madison,WI). Workers' personal exposure to inhalable dust averaged 1.87, 1.40, 2.34, 0.30, and 0.17 mg m(-3) in sintering plant, ferrochromium smelter, stainless steel melting shop, hot rolling mill, and the cold rolling mill, respectively. Particle number concentrations measured using SMPS+C varied from 58 x 10(3) to 662 x 10(3) cm(-3) in the production areas, whereas concentrations measured using SMPS+C and CPC3007 in control rooms ranged from 24 x 10(3) to 243 x 10(3) cm(-3) and 5.1 x 10(3) to 97 x 10(3) cm(-3), respectively. The elemental composition and the structure of particles in different production phases varied. In the cold-rolling mill non-process particles were abundant. In other sites, chromium and iron originating from ore and recycled steel scrap were the most common elements in the particles studied. Particle mass concentrations were at the same level as that reported earlier. However, particle number measurements showed a high amount of ultrafine particles, especially in sintering, alloy smelting and melting, and tapping operations. Particle number concentration and size distribution measurements provide important information regarding exposure to ultrafine particles, which cannot be seen in particle mass measurements. FAU - Jarvela, Merja AU - Jarvela M AD - a Aerosols, Dusts and Metals, Finnish Institute of Occupational Health , Helsinki , Finland. FAU - Huvinen, Markku AU - Huvinen M AD - b Outokumpu Oyj , Espoo , Finland. FAU - Viitanen, Anna-Kaisa AU - Viitanen AK AD - c Nanosafety Research Centre, Finnish Institute of Occupational Health , Tampere , Finland. FAU - Kanerva, Tomi AU - Kanerva T AD - c Nanosafety Research Centre, Finnish Institute of Occupational Health , Tampere , Finland. FAU - Vanhala, Esa AU - Vanhala E AD - a Aerosols, Dusts and Metals, Finnish Institute of Occupational Health , Helsinki , Finland. FAU - Uitti, Jukka AU - Uitti J AD - d Occupational Medicine, Finnish Institute of Occupational Health , Tampere , Finland. FAU - Koivisto, Antti J AU - Koivisto AJ AD - c Nanosafety Research Centre, Finnish Institute of Occupational Health , Tampere , Finland. FAU - Junttila, Sakari AU - Junttila S AD - e Outokumpu Stainless Oy , Tornio , Finland. FAU - Luukkonen, Ritva AU - Luukkonen R AD - f Statistical Services, Finnish Institute of Occupational Health , Helsinki , Finland. FAU - Tuomi, Timo AU - Tuomi T AD - a Aerosols, Dusts and Metals, Finnish Institute of Occupational Health , Helsinki , Finland. LA - eng PT - Journal Article PL - England TA - J Occup Environ Hyg JT - Journal of occupational and environmental hygiene JID - 101189458 RN - 0 (Air Pollutants, Occupational) RN - 0 (Chromium Alloys) RN - 0 (Dust) RN - 0 (Particulate Matter) RN - 0R0008Q3JB (Chromium) RN - 11114-46-8 (ferrochromium) RN - 12597-68-1 (Stainless Steel) RN - E1UOL152H7 (Iron) SB - IM MH - Air Pollutants, Occupational/*analysis MH - Chromium/analysis MH - *Chromium Alloys MH - Dust/analysis MH - Environmental Monitoring MH - Finland MH - Humans MH - Inhalation Exposure/analysis MH - Iron/analysis MH - *Metallurgy MH - Occupational Exposure/*analysis MH - Particle Size MH - Particulate Matter/*analysis MH - *Stainless Steel OTO - NOTNLM OT - Ferrochromium OT - metal industry OT - occupational hygiene OT - particles OT - stainless steel OT - ultrafine particles EDAT- 2016/03/08 06:00 MHDA- 2017/11/09 06:00 CRDT- 2016/03/08 06:00 PHST- 2016/03/08 06:00 [entrez] PHST- 2016/03/08 06:00 [pubmed] PHST- 2017/11/09 06:00 [medline] AID - 10.1080/15459624.2016.1159687 [doi] PST - ppublish SO - J Occup Environ Hyg. 2016 Jul;13(7):558-68. doi: 10.1080/15459624.2016.1159687.