PMID- 26990736
OWN - NLM
STAT- MEDLINE
DCOM- 20161213
LR  - 20220330
IS  - 1873-376X (Electronic)
IS  - 1570-0232 (Linking)
VI  - 1017-1018
DP  - 2016 Apr 1
TI  - Multi-residue analysis of 26 organochlorine pesticides in Alpinia oxyphylla by 
      GC-ECD after solid phase extraction and acid cleanup.
PG  - 211-220
LID - S1570-0232(16)30149-0 [pii]
LID - 10.1016/j.jchromb.2016.03.009 [doi]
AB  - A simple and effective multi-residue method was developed and validated for the 
      analysis of 26 organochlorine pesticide residues in Alpinia oxyphylla by a gas 
      chromatography with an electron capture detector (GC-ECD). The target pesticides 
      were extracted by sonication and cleaned up with florisil solid phase extraction 
      and sulphuric acid. Some crucial parameters, including extraction solvent and 
      time, sorbent type, elute solvent and concentration of sulphuric acid were 
      optimized to improve the performance of sample preparation procedure. The 
      optimized method gave high sensitivity with detection limit ranging from 0.1 to 
      2.0mug/kg. Matrix-matched calibration was employed for the quantification, and a 
      wide linear range (from 1.0 to 1000mug/kg) with r(2) values ranging from 0.9971 to 
      0.9998 was obtained. For the majority of the tested pesticides, the average 
      recoveries were in acceptable range (between 70% and 110%) with relative standard 
      deviation values below 15.0%. Matrix effect was evaluated for target compounds 
      through the study of ratio of peak area obtained in the solvent and blank matrix. 
      The proposed method was applied to simultaneously analyze 26 pesticides in 55 
      batches of Alpinia oxyphylla samples. 3 samples were found to be positive with 
      four pesticides (alpha-BHC, quintozene, trans-chlordane and op'-DDD), which were 
      confirmed by gas chromatography-mass spectrometry (GC-MS) in selective ion 
      monitoring (SIM) mode.
CI  - Copyright (c) 2016 Elsevier B.V. All rights reserved.
FAU - Zhao, Xiangsheng
AU  - Zhao X
AD  - Hainan Branch Institute of Medicinal Plant Development, Chinese Academy of 
      Medical Sciences & Peking Union Medical College, Wanning 571533, China.
FAU - Zhou, Yakui
AU  - Zhou Y
AD  - Hainan Branch Institute of Medicinal Plant Development, Chinese Academy of 
      Medical Sciences & Peking Union Medical College, Wanning 571533, China.
FAU - Kong, Weijun
AU  - Kong W
AD  - Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences & 
      Peking Union Medical College, Beijing 100193, China.
FAU - Gong, Bao
AU  - Gong B
AD  - Hainan Branch Institute of Medicinal Plant Development, Chinese Academy of 
      Medical Sciences & Peking Union Medical College, Wanning 571533, China.
FAU - Chen, Deli
AU  - Chen D
AD  - Hainan Branch Institute of Medicinal Plant Development, Chinese Academy of 
      Medical Sciences & Peking Union Medical College, Wanning 571533, China.
FAU - Wei, Jianhe
AU  - Wei J
AD  - Hainan Branch Institute of Medicinal Plant Development, Chinese Academy of 
      Medical Sciences & Peking Union Medical College, Wanning 571533, China; Institute 
      of Medicinal Plant Development, Chinese Academy of Medical Sciences & Peking 
      Union Medical College, Beijing 100193, China. Electronic address: 
      jhwei@implad.ac.cn.
FAU - Yang, Meihua
AU  - Yang M
AD  - Hainan Branch Institute of Medicinal Plant Development, Chinese Academy of 
      Medical Sciences & Peking Union Medical College, Wanning 571533, China; Institute 
      of Medicinal Plant Development, Chinese Academy of Medical Sciences & Peking 
      Union Medical College, Beijing 100193, China. Electronic address: 
      yangmeihua15@hotmail.com.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20160309
PL  - Netherlands
TA  - J Chromatogr B Analyt Technol Biomed Life Sci
JT  - Journal of chromatography. B, Analytical technologies in the biomedical and life 
      sciences
JID - 101139554
RN  - 0 (Acids)
RN  - 0 (Hydrocarbons, Chlorinated)
RN  - 0 (Pesticide Residues)
SB  - IM
MH  - Acids/*isolation & purification
MH  - Alpinia/*chemistry
MH  - Chromatography, Gas/*methods
MH  - Hydrocarbons, Chlorinated/*analysis
MH  - Pesticide Residues/*analysis
MH  - Solid Phase Microextraction/*methods
OTO - NOTNLM
OT  - Alpinia oxyphylla
OT  - Gas chromatography-electron capture detection
OT  - Organochlorine pesticides
OT  - Solid-phased extraction
EDAT- 2016/03/19 06:00
MHDA- 2016/12/15 06:00
CRDT- 2016/03/19 06:00
PHST- 2015/11/06 00:00 [received]
PHST- 2016/02/24 00:00 [revised]
PHST- 2016/03/07 00:00 [accepted]
PHST- 2016/03/19 06:00 [entrez]
PHST- 2016/03/19 06:00 [pubmed]
PHST- 2016/12/15 06:00 [medline]
AID - S1570-0232(16)30149-0 [pii]
AID - 10.1016/j.jchromb.2016.03.009 [doi]
PST - ppublish
SO  - J Chromatogr B Analyt Technol Biomed Life Sci. 2016 Apr 1;1017-1018:211-220. doi: 
      10.1016/j.jchromb.2016.03.009. Epub 2016 Mar 9.