PMID- 27001527 OWN - NLM STAT- MEDLINE DCOM- 20180919 LR - 20181004 IS - 1364-5528 (Electronic) IS - 0003-2654 (Linking) VI - 141 IP - 12 DP - 2016 Jun 21 TI - Shell-isolated nanoparticle-enhanced Raman spectroscopy study of the adsorption behaviour of DNA bases on Au(111) electrode surfaces. PG - 3731-6 LID - 10.1039/c6an00180g [doi] AB - For the first time, we used the electrochemical shell-isolated nanoparticle-enhanced Raman spectroscopy (EC-SHINERS) technique to in situ characterize the adsorption behaviour of four DNA bases (adenine, guanine, thymine, and cytosine) on atomically flat Au(111) electrode surfaces. The spectroscopic results of the various molecules reveal similar features, such as the adsorption-induced reconstruction of the Au(111) surface and the drastic Raman intensity reduction of the ring breathing modes after the lifting reconstruction. As a preliminary study of the photo-induced charge transfer (PICT) mechanism, the in situ spectroscopic results obtained on single crystal surfaces are excellently illustrated with electrochemical data. FAU - Wen, Bao-Ying AU - Wen BY AD - MOE Key Laboratory of Spectrochemical Analysis and Instrumentation, State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China. li@xmu.edu.cn xuqingchi@xmu.edu.cn. FAU - Jin, Xi AU - Jin X FAU - Li, Yue AU - Li Y FAU - Wang, Ya-Hao AU - Wang YH FAU - Li, Chao-Yu AU - Li CY FAU - Liang, Miao-Miao AU - Liang MM FAU - Panneerselvam, Rajapandiyan AU - Panneerselvam R FAU - Xu, Qing-Chi AU - Xu QC FAU - Wu, De-Yin AU - Wu DY FAU - Yang, Zhi-Lin AU - Yang ZL FAU - Li, Jian-Feng AU - Li JF FAU - Tian, Zhong-Qun AU - Tian ZQ LA - eng PT - Journal Article DEP - 20160322 PL - England TA - Analyst JT - The Analyst JID - 0372652 RN - 7440-57-5 (Gold) RN - 9007-49-2 (DNA) SB - IM MH - Adsorption MH - DNA/*chemistry MH - Electrodes MH - *Gold MH - *Nanoparticles MH - *Spectrum Analysis, Raman EDAT- 2016/03/24 06:00 MHDA- 2018/09/20 06:00 CRDT- 2016/03/23 06:00 PHST- 2016/03/23 06:00 [entrez] PHST- 2016/03/24 06:00 [pubmed] PHST- 2018/09/20 06:00 [medline] AID - 10.1039/c6an00180g [doi] PST - ppublish SO - Analyst. 2016 Jun 21;141(12):3731-6. doi: 10.1039/c6an00180g. Epub 2016 Mar 22.