PMID- 27032407
OWN - NLM
STAT- MEDLINE
DCOM- 20180112
LR  - 20191210
IS  - 1618-2650 (Electronic)
IS  - 1618-2642 (Linking)
VI  - 408
IP  - 15
DP  - 2016 Jun
TI  - Polydopamine-coated magnetic nanoparticles for isolation and enrichment of 
      estrogenic compounds from surface water samples followed by liquid 
      chromatography-tandem mass spectrometry determination.
PG  - 4011-20
LID - 10.1007/s00216-016-9489-9 [doi]
AB  - Estrogens, phytoestrogens, and mycoestrogens may enter into the surface waters 
      from different sources, such as effluents of municipal wastewater treatment 
      plants, industrial plants, and animal farms and runoff from agricultural areas. 
      In this work, a multiresidue analytical method for the determination of 17 
      natural estrogenic compounds, including four steroid estrogens, six 
      mycoestrogens, and seven phytoestrogens, in river water samples has been 
      developed. (Fe3O4)-based magnetic nanoparticles coated by polydopamine 
      (Fe3O4@pDA) were used for dispersive solid-phase extraction, and the final 
      extract was analyzed by ultra-high performance liquid chromatography coupled with 
      tandem mass spectrometry. The Fe3O4 magnetic nanoparticles were prepared by a 
      co-precipitation procedure, coated by pDA, and characterized by scanning electron 
      microscopy, infrared spectroscopy, and elemental analysis. The sample preparation 
      method was optimized in terms of extraction recovery, matrix effect, selectivity, 
      trueness, precision, method limits of detection, and method limits of 
      quantification (MLOQs). For all the 17 analytes, recoveries were >70 % and matrix 
      effects were below 30 % when 25 mL of river water sample was treated with 90 mg 
      of Fe3O4@pDA nanoparticles. Selectivity was tested by spiking river water samples 
      with 50 other compounds (mycotoxins, antibacterials, conjugated hormones, UV 
      filters, alkylphenols, etc.), and only aflatoxins and some benzophenones showed 
      recoveries >60 %. This method proved to be simple and robust and allowed the 
      determination of natural estrogenic compounds belonging to different classes in 
      surface waters with MLOQs ranging between 0.003 and 0.1 mug L(-1). Graphical 
      Abstract Determination of natural estrogenic compounds in water by magnetic solid 
      phase extraction followed by liquid chromatography-tandem mass spectrometry 
      analysis.
FAU - Capriotti, Anna Laura
AU  - Capriotti AL
AD  - Dipartimento di Chimica, Universita di Roma "La Sapienza", Piazzale Aldo Moro 5, 
      00185, Rome, Italy.
FAU - Cavaliere, Chiara
AU  - Cavaliere C
AD  - Dipartimento di Chimica, Universita di Roma "La Sapienza", Piazzale Aldo Moro 5, 
      00185, Rome, Italy. chiara.cavaliere@uniroma1.it.
FAU - La Barbera, Giorgia
AU  - La Barbera G
AD  - Dipartimento di Chimica, Universita di Roma "La Sapienza", Piazzale Aldo Moro 5, 
      00185, Rome, Italy.
FAU - Piovesana, Susy
AU  - Piovesana S
AD  - Dipartimento di Chimica, Universita di Roma "La Sapienza", Piazzale Aldo Moro 5, 
      00185, Rome, Italy.
FAU - Samperi, Roberto
AU  - Samperi R
AD  - Dipartimento di Chimica, Universita di Roma "La Sapienza", Piazzale Aldo Moro 5, 
      00185, Rome, Italy.
FAU - Zenezini Chiozzi, Riccardo
AU  - Zenezini Chiozzi R
AD  - Dipartimento di Chimica, Universita di Roma "La Sapienza", Piazzale Aldo Moro 5, 
      00185, Rome, Italy.
FAU - Lagana, Aldo
AU  - Lagana A
AD  - Dipartimento di Chimica, Universita di Roma "La Sapienza", Piazzale Aldo Moro 5, 
      00185, Rome, Italy.
LA  - eng
PT  - Evaluation Study
PT  - Journal Article
DEP - 20160331
PL  - Germany
TA  - Anal Bioanal Chem
JT  - Analytical and bioanalytical chemistry
JID - 101134327
RN  - 0 (Estrogens)
RN  - 0 (Indoles)
RN  - 0 (Magnetite Nanoparticles)
RN  - 0 (Polymers)
RN  - 0 (Water Pollutants, Chemical)
RN  - 0 (polydopamine)
SB  - IM
MH  - Adsorption
MH  - Chromatography, Liquid/*methods
MH  - Estrogens/*chemistry/isolation & purification
MH  - Indoles/chemistry
MH  - Magnetite Nanoparticles/*chemistry
MH  - Polymers/chemistry
MH  - Tandem Mass Spectrometry/*methods
MH  - Water Pollutants, Chemical/*chemistry/isolation & purification
OTO - NOTNLM
OT  - Dispersive solid-phase extraction
OT  - Estrogens
OT  - Magnetic nanoparticles
OT  - Mycoestrogens
OT  - Phytoestrogens
OT  - Polydopamine
EDAT- 2016/04/02 06:00
MHDA- 2018/01/13 06:00
CRDT- 2016/04/02 06:00
PHST- 2016/01/27 00:00 [received]
PHST- 2016/03/14 00:00 [accepted]
PHST- 2016/03/07 00:00 [revised]
PHST- 2016/04/02 06:00 [entrez]
PHST- 2016/04/02 06:00 [pubmed]
PHST- 2018/01/13 06:00 [medline]
AID - 10.1007/s00216-016-9489-9 [pii]
AID - 10.1007/s00216-016-9489-9 [doi]
PST - ppublish
SO  - Anal Bioanal Chem. 2016 Jun;408(15):4011-20. doi: 10.1007/s00216-016-9489-9. Epub 
      2016 Mar 31.