PMID- 27043880
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20170519
LR  - 20170908
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 312
DP  - 2016 Jul 15
TI  - Selection of oxidant doses for in situ chemical oxidation of soils contaminated 
      by polycyclic aromatic hydrocarbons (PAHs): A review.
PG  - 280-297
LID - S0304-3894(16)30290-4 [pii]
LID - 10.1016/j.jhazmat.2016.03.068 [doi]
AB  - In situ chemical oxidation (ISCO) is a promising alternative to thermal 
      desorption for the remediation of soils contaminated with organic compounds such 
      as polycyclic aromatic hydrocarbons (PAHs). For field application, one major 
      issue is the selection of the optimal doses of the oxidizing solution, i.e. the 
      oxidant and appropriate catalysts and/or additives. Despite an extensive 
      scientific literature on ISCO, this choice is very difficult because many 
      parameters differ from one study to another. The present review identifies the 
      critical factors that must be taken into account to enable comparison of these 
      various contributions. For example, spiked soils and aged, polluted soils cannot 
      be compared; PAHs freshly spiked into a soil are fully available for degradation 
      unlike a complex mixture of pollutants trapped in a soil for many years. Another 
      notable example is the high diversity of oxidation conditions employed during 
      batch experiments, although these affect the representativeness of the system. 
      Finally, in this review a methodology is also proposed based on a combination of 
      the stoichiometric oxidant demand of the organic pollutants and the design of 
      experiments (DOE) in order to allow a better comparison of the various studies so 
      far reported.
CI  - Copyright (c) 2016 Elsevier B.V. All rights reserved.
FAU - Ranc, B
AU  - Ranc B
AD  - Universite de Lorraine, Laboratoire Interdisciplinaire des Environnements 
      Continentaux, UMR 7360, Site Aiguillette, 54506 Vandoeuvre-les-Nancy cedex, 
      France; CNRS, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR 
      7360, Site Aiguillettes, 54506 Vandoeuvre-les-Nancy cedex, France; ICF 
      Environnement, 14 a 30 rue Alexandre, 92635 Gennevilliers, France; Universite de 
      Lorraine, Laboratoire Reactions et Genie des Procedes, UMR 7274, 1 rue 
      Grandville, 54001 Nancy cedex, France; CNRS, Laboratoire Reactions et Genie des 
      Procedes, UMR 7274, 1 rue Grandville, 54001 Nancy cedex, France.
FAU - Faure, P
AU  - Faure P
AD  - Universite de Lorraine, Laboratoire Interdisciplinaire des Environnements 
      Continentaux, UMR 7360, Site Aiguillette, 54506 Vandoeuvre-les-Nancy cedex, 
      France; CNRS, Laboratoire Interdisciplinaire des Environnements Continentaux, UMR 
      7360, Site Aiguillettes, 54506 Vandoeuvre-les-Nancy cedex, France.
FAU - Croze, V
AU  - Croze V
AD  - ICF Environnement, 14 a 30 rue Alexandre, 92635 Gennevilliers, France.
FAU - Simonnot, M O
AU  - Simonnot MO
AD  - Universite de Lorraine, Laboratoire Reactions et Genie des Procedes, UMR 7274, 1 
      rue Grandville, 54001 Nancy cedex, France; CNRS, Laboratoire Reactions et Genie 
      des Procedes, UMR 7274, 1 rue Grandville, 54001 Nancy cedex, France. Electronic 
      address: marie-odile.simonnot@univ-lorraine.fr.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PT  - Review
DEP - 20160326
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
OTO - NOTNLM
OT  - Design of experiments (DOE)
OT  - In situ chemical oxidation (ISCO)
OT  - Oxidant dose
OT  - PAH-contaminated soil
OT  - Stoichiometric oxidant demand
EDAT- 2016/04/05 06:00
MHDA- 2016/04/05 06:01
CRDT- 2016/04/05 06:00
PHST- 2015/04/09 00:00 [received]
PHST- 2016/03/23 00:00 [revised]
PHST- 2016/03/25 00:00 [accepted]
PHST- 2016/04/05 06:00 [entrez]
PHST- 2016/04/05 06:00 [pubmed]
PHST- 2016/04/05 06:01 [medline]
AID - S0304-3894(16)30290-4 [pii]
AID - 10.1016/j.jhazmat.2016.03.068 [doi]
PST - ppublish
SO  - J Hazard Mater. 2016 Jul 15;312:280-297. doi: 10.1016/j.jhazmat.2016.03.068. Epub 
      2016 Mar 26.