PMID- 27054736 OWN - NLM STAT- MEDLINE DCOM- 20160614 LR - 20221207 IS - 0273-1223 (Print) IS - 0273-1223 (Linking) VI - 73 IP - 7 DP - 2016 TI - Evaluation of the role of inherent Ca(2+) in phosphorus removal from wastewater system. PG - 1644-51 LID - 10.2166/wst.2015.642 [doi] AB - The role of inherent Ca(2+) in phosphorus removal from wastewater was evaluated by batch tests. Precipitates were characterized by an X-ray diffractometer (XRD), Fourier transform infrared spectrophotometer (FT-IR) and scanning electron microscope with an energy dispersive spectrometer (EDS) system. Effects of inherent Ca(2+) on phosphorus removal through basic oxygen furnace slag (BOFS) were also analyzed. The results show that upon adjusting the pH to higher than 7.0, inherent Ca(2+) can remove phosphorus from wastewater and form Ca-P precipitates. Residual phosphorus exhibited a linear decreasing trend with increasing the pH from 7.0 to 10.0 and then remained unchanged at higher pH than 10.0. EDS determined that the precipitates contained the elements Ca, P and O. FT-IR spectra demonstrated that the functional groups of precipitates involved PO4(3-), OH(-) and CO3(2-). XRD indicated that the precipitates may consist of CaCO3 and some Ca-P phosphates such as CaHPO4, Ca4H(PO4)3, Ca3(PO4)2, and Ca5(PO4)3(OH). During the removal process of phosphorus by BOFS, due to the presence of inherent Ca(2+) in wastewater, the removal efficiency and rate of phosphorus increased by 15.5% and by a factor of about 3.0, respectively. FAU - Han, Chong AU - Han C AD - School of Metallurgy, Northeastern University, Shenyang 110819, China E-mail: hanch@smm.neu.edu.cn. FAU - Wang, Zhen AU - Wang Z AD - School of Metallurgy, Northeastern University, Shenyang 110819, China E-mail: hanch@smm.neu.edu.cn. FAU - Wu, Qianqian AU - Wu Q AD - School of Metallurgy, Northeastern University, Shenyang 110819, China E-mail: hanch@smm.neu.edu.cn. FAU - Yang, Wangjin AU - Yang W AD - School of Metallurgy, Northeastern University, Shenyang 110819, China E-mail: hanch@smm.neu.edu.cn. FAU - Yang, He AU - Yang H AD - School of Metallurgy, Northeastern University, Shenyang 110819, China E-mail: hanch@smm.neu.edu.cn. FAU - Xue, Xiangxin AU - Xue X AD - School of Metallurgy, Northeastern University, Shenyang 110819, China E-mail: hanch@smm.neu.edu.cn. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - England TA - Water Sci Technol JT - Water science and technology : a journal of the International Association on Water Pollution Research JID - 9879497 RN - 0 (Phosphates) RN - 0 (Waste Water) RN - 27YLU75U4W (Phosphorus) RN - H0G9379FGK (Calcium Carbonate) RN - S88TT14065 (Oxygen) RN - SY7Q814VUP (Calcium) SB - IM MH - Calcium/*chemistry MH - Calcium Carbonate/chemistry MH - Oxygen MH - Phosphates/*chemistry MH - Phosphorus/*chemistry MH - Spectroscopy, Fourier Transform Infrared MH - Waste Disposal Facilities MH - Wastewater/*chemistry MH - Water Purification EDAT- 2016/04/08 06:00 MHDA- 2016/06/15 06:00 CRDT- 2016/04/08 06:00 PHST- 2016/04/08 06:00 [entrez] PHST- 2016/04/08 06:00 [pubmed] PHST- 2016/06/15 06:00 [medline] AID - 10.2166/wst.2015.642 [doi] PST - ppublish SO - Water Sci Technol. 2016;73(7):1644-51. doi: 10.2166/wst.2015.642.