PMID- 27093495
OWN - NLM
STAT- MEDLINE
DCOM- 20170202
LR  - 20170806
IS  - 1873-376X (Electronic)
IS  - 1570-0232 (Linking)
VI  - 1022
DP  - 2016 Jun 1
TI  - Determination of organophosphorus pesticides in ginseng by carbon nanotube 
      envelope-based solvent extraction combined with ultrahigh-performance liquid 
      chromatography mass spectrometry.
PG  - 141-152
LID - S1570-0232(16)30237-9 [pii]
LID - 10.1016/j.jchromb.2016.04.018 [doi]
AB  - A miniature extraction envelope containing multiwall carbon nanotubes, diatomite, 
      neutral alumina, and anhydrous magnesium sulfate was developed for the solvent 
      extraction of organophosphorus pesticides in dried ginseng. After the powder of 
      dried ginseng sample was introduced into the envelope, the envelope was heat 
      sealed and sonicated in acetonitrile for the extraction and clean-up of analytes. 
      The resulting extracts were analyzed by an ultrahigh-performance liquid 
      chromatograph with an electrospray ion source and a quadrupole orbitrap mass 
      spectrometer (UHPLC-ESI/Q-Orbitrap MS) under target-MS(2) mode, and the analytes 
      were quantified by matrix-match calibration. Finally, the simultaneous 
      identification and quantification of 19 pesticide residues were carried out by 
      the present method. It is noteworthy that in this method the processes of 
      extraction and clean-up for the analytes could be carried out and accomplished in 
      one step. The recoveries and relative standard deviations (RSDs) of analytes were 
      in the range of 82.6-110.8% and 1.0-10.6%, respectively. The limits of detection 
      (LODs) and quantification (LOQs) for analytes were determined to be 
      0.08-0.29mugkg(-1) and 0.26-0.98mugkg(-1), respectively. Several pesticide residues 
      investigated in this study were found in 4 real samples, with the concentrations 
      lower than the maximum residue limit (0.050mgkg(-1)) established by European 
      Union.
CI  - Copyright (c) 2016 Elsevier B.V. All rights reserved.
FAU - Su, Rui
AU  - Su R
AD  - Changchun University of Chinese Medicine, Changchun 130117, China; Department of 
      Chemistry, Jilin University, Changchun 130012, China.
FAU - Li, Dan
AU  - Li D
AD  - Changchun University of Chinese Medicine, Changchun 130117, China.
FAU - Wang, Xinghua
AU  - Wang X
AD  - Department of Chemistry, Jilin University, Changchun 130012, China.
FAU - Yang, Hongmei
AU  - Yang H
AD  - Changchun University of Chinese Medicine, Changchun 130117, China.
FAU - Shi, Xiaoyu
AU  - Shi X
AD  - Changchun University of Chinese Medicine, Changchun 130117, China.
FAU - Liu, Shuying
AU  - Liu S
AD  - Changchun University of Chinese Medicine, Changchun 130117, China. Electronic 
      address: syliu_ginseng@163.com.
LA  - eng
PT  - Journal Article
DEP - 20160408
PL  - Netherlands
TA  - J Chromatogr B Analyt Technol Biomed Life Sci
JT  - Journal of chromatography. B, Analytical technologies in the biomedical and life 
      sciences
JID - 101139554
RN  - 0 (Nanotubes, Carbon)
RN  - 0 (Organophosphorus Compounds)
RN  - 0 (Pesticide Residues)
RN  - 0 (Plant Preparations)
SB  - IM
MH  - Chromatography, High Pressure Liquid/*methods
MH  - Limit of Detection
MH  - Linear Models
MH  - Nanotubes, Carbon/*chemistry
MH  - Organophosphorus Compounds/*analysis/chemistry
MH  - Panax/*chemistry
MH  - Pesticide Residues/*analysis/chemistry
MH  - Plant Preparations/*chemistry
MH  - Reproducibility of Results
OTO - NOTNLM
OT  - Carbon nanotube envelope
OT  - Dried ginseng root
OT  - Organophosphorus pesticides
OT  - UHPLC-ESI/Q-Orbitrap MS
EDAT- 2016/04/20 06:00
MHDA- 2017/02/06 06:00
CRDT- 2016/04/20 06:00
PHST- 2015/12/09 00:00 [received]
PHST- 2016/03/28 00:00 [revised]
PHST- 2016/04/08 00:00 [accepted]
PHST- 2016/04/20 06:00 [entrez]
PHST- 2016/04/20 06:00 [pubmed]
PHST- 2017/02/06 06:00 [medline]
AID - S1570-0232(16)30237-9 [pii]
AID - 10.1016/j.jchromb.2016.04.018 [doi]
PST - ppublish
SO  - J Chromatogr B Analyt Technol Biomed Life Sci. 2016 Jun 1;1022:141-152. doi: 
      10.1016/j.jchromb.2016.04.018. Epub 2016 Apr 8.