PMID- 27143474 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20170914 LR - 20181113 IS - 2045-2322 (Electronic) IS - 2045-2322 (Linking) VI - 6 DP - 2016 May 4 TI - Robust singlet dimers with fragile ordering in two-dimensional honeycomb lattice of Li2RuO3. PG - 25238 LID - 10.1038/srep25238 [doi] LID - 25238 AB - When an electronic system has strong correlations and a large spin-orbit interaction, it often exhibits a plethora of mutually competing quantum phases. How a particular quantum ground state is selected out of several possibilities is a very interesting question. However, equally fascinating is how such a quantum entangled state breaks up due to perturbation. This important question has relevance in very diverse fields of science from strongly correlated electron physics to quantum information. Here we report that a quantum entangled dimerized state or valence bond crystal (VBC) phase of Li2RuO3 shows nontrivial doping dependence as we perturb the Ru honeycomb lattice by replacing Ru with Li. Through extensive experimental studies, we demonstrate that the VBC phase melts into a valence bond liquid phase of the RVB (resonating valence bond) type. This system offers an interesting playground where one can test and refine our current understanding of the quantum competing phases in a single compound. FAU - Park, Junghwan AU - Park J AD - Center for Strongly Correlated Materials Research, Seoul National University, Seoul 08826, Korea. FAU - Tan, Teck-Yee AU - Tan TY AD - Center for Correlated Electron Systems, Institute for Basic Science, Seoul 08826, Korea. FAU - Adroja, D T AU - Adroja DT AD - ISIS Facility, Rutherford Appleton Laboratory, Didcot OX11 0QX, United Kingdom. AD - Highly Correlated Matter Research Group, Physics Department, University of Johannesburg, Auckland Park 2006, South Africa. FAU - Daoud-Aladine, A AU - Daoud-Aladine A AD - ISIS Facility, Rutherford Appleton Laboratory, Didcot OX11 0QX, United Kingdom. FAU - Choi, Seongil AU - Choi S AD - Center for Strongly Correlated Materials Research, Seoul National University, Seoul 08826, Korea. AD - Center for Correlated Electron Systems, Institute for Basic Science, Seoul 08826, Korea. FAU - Cho, Deok-Yong AU - Cho DY AD - Center for Strongly Correlated Materials Research, Seoul National University, Seoul 08826, Korea. AD - Center for Correlated Electron Systems, Institute for Basic Science, Seoul 08826, Korea. FAU - Lee, Sang-Hyun AU - Lee SH AD - Center for Strongly Correlated Materials Research, Seoul National University, Seoul 08826, Korea. AD - Center for Correlated Electron Systems, Institute for Basic Science, Seoul 08826, Korea. FAU - Kim, Jiyeon AU - Kim J AD - Center for Strongly Correlated Materials Research, Seoul National University, Seoul 08826, Korea. FAU - Sim, Hasung AU - Sim H AD - Center for Correlated Electron Systems, Institute for Basic Science, Seoul 08826, Korea. AD - Department of Physics and Astronomy, Seoul National University, Seoul 08826, Korea. FAU - Morioka, T AU - Morioka T AD - Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan. FAU - Nojiri, H AU - Nojiri H AD - Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan. FAU - Krishnamurthy, V V AU - Krishnamurthy VV AD - Department of Physics and Astronomy, George Mason University, Fairfax, VA 22030-4444, USA. FAU - Manuel, P AU - Manuel P AD - ISIS Facility, Rutherford Appleton Laboratory, Didcot OX11 0QX, United Kingdom. FAU - Lees, M R AU - Lees MR AD - Department of Physics, University of Warwick, Coventry CV4 7AL, United Kingdom. FAU - Streltsov, S V AU - Streltsov SV AD - Institute of Metal Physics, Ekaterinburg 620041, Russia. AD - Department of Theoretical Physics and Applied Mathematics, Ural Federal University, Ekaterinburgh 620002, Russia. FAU - Khomskii, D I AU - Khomskii DI AD - II Physikalisches Institut, University of Koeln, 50937 Koeln, Germany. FAU - Park, Je-Geun AU - Park JG AD - Center for Strongly Correlated Materials Research, Seoul National University, Seoul 08826, Korea. AD - Center for Correlated Electron Systems, Institute for Basic Science, Seoul 08826, Korea. AD - Department of Physics and Astronomy, Seoul National University, Seoul 08826, Korea. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20160504 PL - England TA - Sci Rep JT - Scientific reports JID - 101563288 PMC - PMC4855220 EDAT- 2016/05/05 06:00 MHDA- 2016/05/05 06:01 PMCR- 2016/05/04 CRDT- 2016/05/05 06:00 PHST- 2016/01/19 00:00 [received] PHST- 2016/04/13 00:00 [accepted] PHST- 2016/05/05 06:00 [entrez] PHST- 2016/05/05 06:00 [pubmed] PHST- 2016/05/05 06:01 [medline] PHST- 2016/05/04 00:00 [pmc-release] AID - srep25238 [pii] AID - 10.1038/srep25238 [doi] PST - epublish SO - Sci Rep. 2016 May 4;6:25238. doi: 10.1038/srep25238.