PMID- 27166780 OWN - NLM STAT- MEDLINE DCOM- 20180820 LR - 20180820 IS - 1873-3336 (Electronic) IS - 0304-3894 (Linking) VI - 323 IP - Pt A DP - 2017 Feb 5 TI - Fate and mass balance of triclosan and its degradation products: Comparison of three different types of wastewater treatments and aerobic/anaerobic sludge digestion. PG - 329-340 LID - S0304-3894(16)30375-2 [pii] LID - 10.1016/j.jhazmat.2016.04.034 [doi] AB - Triclosan (TCS) as an antimicrobial agent has been ubiquitously found in wastewater and sewage sludge. TCS may undergo transformation/degradation during wastewater treatment. Some of the resulted products such as 2,4-dichlorophenol (2,4-DCP), 2,8-dichlorodibenzoparadioxin (2,8-DCDD) and methyl triclosan (MTCS) are presumed toxic/persistent compounds. In this study, fate of TCS and the probability of formation of important degradation products were investigated in three susceptible wastewater/sludge treatment practices. 24.1% and 27.2% of the loading TCS was adsorbed to the generated sludge, whereas up to 60% of the loading TCS was biotransformed. Up to 9.9% and 13.0% of TCS loss was attributed to the formation of 2,4-DCP and 2,8-DCDD in chlorination and UV disinfection, respectively. Anaerobic and aerobic sludge digestion processes eliminated up to 23.0% and 56.0% of TCS, respectively. About 7.4% of TCS in aerobic digestion was transformed to methyl triclosan (MTCS). Significant temporal variation of TCS was observed in primary sedimentations, except for chemically enhanced primary treatment that was suggested to be governed by chemical-forced sedimentation. Distribution coefficient (K(d)) of TCS was directly correlated to the total organic carbon of the sludge (TOC). Moreover, strong correlation was observed between elimination efficiency in primary sedimentation and loading concentration. CI - Copyright A(c) 2016 Elsevier B.V. All rights reserved. FAU - Tohidi, Fatemeh AU - Tohidi F AD - State Key Laboratory of Environment and Biological Analysis, Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China. FAU - Cai, Zongwei AU - Cai Z AD - State Key Laboratory of Environment and Biological Analysis, Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China; School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou, China. Electronic address: zwcai@hkbu.edu.hk. LA - eng PT - Comparative Study PT - Journal Article DEP - 20160427 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 RN - 0 (Sewage) RN - 4NM5039Y5X (Triclosan) RN - 7440-44-0 (Carbon) SB - IM MH - Aerobiosis MH - Algorithms MH - Anaerobiosis MH - Biodegradation, Environmental MH - Carbon/analysis MH - Halogenation MH - Seasons MH - Sewage/*analysis MH - Temperature MH - Triclosan/*analysis MH - Ultraviolet Rays MH - Waste Disposal, Fluid/*methods OTO - NOTNLM OT - 2,4-Dicholorophenol OT - 2,8-Dichlorodibenzoparadioxin OT - Biodegradation OT - Distribution coefficient OT - Mass balance OT - Sewage treatment plant OT - Triclosan EDAT- 2016/05/12 06:00 MHDA- 2018/08/21 06:00 CRDT- 2016/05/12 06:00 PHST- 2016/01/28 00:00 [received] PHST- 2016/04/12 00:00 [revised] PHST- 2016/04/13 00:00 [accepted] PHST- 2016/05/12 06:00 [pubmed] PHST- 2018/08/21 06:00 [medline] PHST- 2016/05/12 06:00 [entrez] AID - S0304-3894(16)30375-2 [pii] AID - 10.1016/j.jhazmat.2016.04.034 [doi] PST - ppublish SO - J Hazard Mater. 2017 Feb 5;323(Pt A):329-340. doi: 10.1016/j.jhazmat.2016.04.034. Epub 2016 Apr 27.